Ruthenium catalysts for the Kharasch reaction

被引：138

作者：

Severin, K ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

CURRENT ORGANIC CHEMISTRY | 2006年 / 10卷 / 02期

关键词：

D O I：

10.2174/138527206775192915

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Recent advances in the development of ruthenium catalysts for the atom transfer radical addition of polyhalogenated compounds to olefins ('Kharasch reaction') are described. Three classes of homogeneous catalysts are discussed: halfsandwich complexes with eta(6)-arene, eta(5)-cyclopentadienyl or eta(5)-carborane ligands, ruthenium complexes with alkylidene- or vinylidene ligands and polynuclear complexes. Furthermore, first attempts to use immobilized ruthenium complexes as heterogeneous catalysts for the Kharasch reaction are summarized.

引用

页码：217 / 224

页数：8

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