Excess volumes, densities, speeds of sound, and viscosities for the binary systems of 1-octanol with hexadecane and squalane at (298.15, 303.15 and 308.15) K

被引:30
作者
Dubey, Gyan P. [1 ]
Sharma, Monika [1 ]
机构
[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India
关键词
apparent molar volume; binary mixtures; density; excess volumes; hexadecane; isentropic compressibility; 1-octanol; PFP theory; speed of sound; squalane; viscosity;
D O I
10.1007/s10765-008-0491-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar volumes, V-m(E), excess molar isentropic compressibilities, K-S, m(E), and deviations of the speeds of sound, u(D), from their ideal values u(id) in an ideal mixture for binary mixtures of 1-octanol, C8H17OH, with hexadecane, C16H34, and squalane (2,6,10,15,19,23-hexamethyltetracosane), C30H62, at T =(298.15, 303.15, 308.15) K and at atmospheric pressure were derived from experimental density, rho, and speed-of-sound data, u. Viscosity measurements were also carried out for the same mixtures. The Prigogine-Flory-Patterson (PFP) theory has been applied to analyze V-m(E) of these systems. Furthermore, the apparent molar volumes, (V) over bar (0)(phi,i) and apparent molar compressibility, (K) over bar (0)(phi,i) of the components at infinite dilution have been calculated.
引用
收藏
页码:1361 / 1375
页数:15
相关论文
共 51 条
[1]   THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].
ABE, A ;
FLORY, PJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) :1838-&
[2]   Acoustical and excess properties of {chlorobenzene plus 1-hexanol, or 1-heptanol, or 1-octanol, or 1-nonanol, or 1-decanol} at (298.15, 303.15, 308.15, and 313.15) K [J].
Al-Jimaz, Adel S. ;
Al-Kandary, Jasem A. ;
Abdul-Latif, Abdul-Haq M. .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (01) :206-214
[3]   POLARIZABILITY AND MOLECULAR RADIUS OF BROMOFORM AND HYDROCARBON LIQUIDS [J].
AMINABHAVI, TM ;
ARALAGUPPI, MI ;
HAROGOPPAD, SB ;
BALUNDGI, RH .
FLUID PHASE EQUILIBRIA, 1992, 72 :211-225
[4]   DENSITIES, VISCOSITIES, REFRACTIVE-INDEXES, AND SPEEDS OF SOUND OF THE BINARY-MIXTURES OF BIS(2-METHOXYETHYL) ETHER WITH NONANE, DECANE, DODECANE, TETRADECANE, AND HEXADECANE AT 298.15-K, 308.15-K, AND 318.15-K [J].
AMINABHAVI, TM ;
GOPALKRISHNA, B .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (03) :529-534
[5]   THERMODYNAMIC INTERACTIONS IN MIXTURES OF BROMOFORM WITH HYDROCARBONS [J].
ARALAGUPPI, MI ;
AMINABHAVI, TM ;
BALUNDGI, RH ;
JOSHI, SS .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (13) :5299-5308
[6]   Speed of sound of n-hexane and n-hexadecane at temperatures between 298 and 373 K and pressures up to 100 MPa [J].
Ball, SJ ;
Trusler, JPM .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2001, 22 (02) :427-443
[7]   EVALUATION OF EXCESS ISENTROPIC COMPRESSIBILITIES AND ISOCHORIC HEAT-CAPACITIES [J].
BENSON, GC ;
KIYOHARA, O .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1979, 11 (11) :1061-1064
[8]   ULTRASONIC SPEEDS AND ISENTROPIC COMPRESSIBILITIES FOR (DECAN-1-OL + NORMAL-ALKANE) AT 298.15-K [J].
BENSON, GC ;
HANDA, YP .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1981, 13 (09) :887-896
[9]   Temperature dependence of the speed of sound, densities, and isentropic compressibilities of hexane plus hexadecane in the range of (293.15 to 373.15) K [J].
Bolotnikov, MF ;
Neruchev, YA ;
Melikhov, YF ;
Verveyko, VN ;
Verveyko, MV .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (03) :1095-1098
[10]   Isobaric thermal expansivity and thermophysical characterization of liquids and liquid mixtures [J].
Cerdeiriña, CA ;
Tovar, CA ;
González-Salgado, D ;
Carballo, E ;
Romaní, L .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2001, 3 (23) :5230-5236