Excess volumes, densities, speeds of sound, and viscosities for the binary systems of 1-octanol with hexadecane and squalane at (298.15, 303.15 and 308.15) K

被引:30
|
作者
Dubey, Gyan P. [1 ]
Sharma, Monika [1 ]
机构
[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India
关键词
apparent molar volume; binary mixtures; density; excess volumes; hexadecane; isentropic compressibility; 1-octanol; PFP theory; speed of sound; squalane; viscosity;
D O I
10.1007/s10765-008-0491-0
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess molar volumes, V-m(E), excess molar isentropic compressibilities, K-S, m(E), and deviations of the speeds of sound, u(D), from their ideal values u(id) in an ideal mixture for binary mixtures of 1-octanol, C8H17OH, with hexadecane, C16H34, and squalane (2,6,10,15,19,23-hexamethyltetracosane), C30H62, at T =(298.15, 303.15, 308.15) K and at atmospheric pressure were derived from experimental density, rho, and speed-of-sound data, u. Viscosity measurements were also carried out for the same mixtures. The Prigogine-Flory-Patterson (PFP) theory has been applied to analyze V-m(E) of these systems. Furthermore, the apparent molar volumes, (V) over bar (0)(phi,i) and apparent molar compressibility, (K) over bar (0)(phi,i) of the components at infinite dilution have been calculated.
引用
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页码:1361 / 1375
页数:15
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