Electrocatalytic behaviour of carbon paste electrode modified with iron(II) phthalocyanine (FePc) nanoparticles towards the detection of amitrole

This paper describes the construction of a carbon paste electrode (CPE) impregnated with nanoparticles of iron(II) phthalocyanine (nanoFePc). The new electrode (nanoFePc-CPE) revealed interesting electrocatalytic behaviour towards amitrole; pure catalytic diffusion-controlled process, with high Tafel slope (235 mV/decade) suggesting strong binding of amitrole with nanoFePc catalyst. The effects of catalyst loading, varying pH and electrolytes were studied. The mechanism for the interaction of amitrole with the nanoFePc is proposed to involve the (FePc)-Pc-(III)/(FePc)-Pc-(II) redox process. Using chronoamperometry (E = +0.42 V versus Ag/AgCl) technique, the sensor was reliably employed for amitrole assay at pH 12.0 phosphate buffer (with sodium sulphate as the supporting electrolyte) for up to 12 nM antitrole with excellent sensitivity (ca. 3.44 mu A/nM) and low detection limit (3.62 +/- 0.11 nM, i.e. 0.305 mu g L-1 using the Y-B + 3(sigma B) criterion and 0.85 +/- 0.03 nM, i.e. 70 ng/L with the Y-B + 2(sigma B) criterion) as well as satisfactory amperometric selectivity coefficient (K-amp approximate to 7.4 x 10(-4) for ammonium thiocyanate, a component of many amitrole herbicides, and 3.2 x 10(-3) for asulam pesticide). The surface of the electrode can easily be regenerated by simple polishing on an alumina paper, obtaining a fresh surface ready for use in a new assay. The proposed electrode was successfully applied in the quantification of amitrole in its commercial formulation as well as in tap water samples. (c) 2005 Elsevier B.V. All rights reserved.