High-Performance and Stable Perovskite Solar Cells Using Carbon Quantum Dots and Upconversion Nanoparticles

被引:11
作者
Alkahtani, Masfer [1 ]
Alenzi, Sultan M. [2 ]
Alsolami, Abdulellah [3 ]
Alsofyani, Najla [1 ]
Alfahd, Anfal [1 ]
Alzahrani, Yahya A. [1 ,3 ]
Aljuwayr, Abdulaziz [1 ]
Abduljawad, Marwan [3 ]
机构
[1] King Abdulaziz City Sci & Technol KACST, Natl Ctr Renewable Energy, Riyadh 11442, Saudi Arabia
[2] King Abdulaziz City Sci & Technol KACST, Natl Ctr Nanotechnol & Semicond, Riyadh 11442, Saudi Arabia
[3] King Abdulaziz City Sci & Technol KACST, Mat Sci Res Inst MSRI, Natl Petrochem Technol Ctr NPTC, Riyadh 11442, Saudi Arabia
关键词
carbon quantum dots; upconversion nanoparticles; lithium; perovskite solar cells; TRIHALIDE; CRYSTAL; LENGTHS;
D O I
10.3390/ijms232214441
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Upconversion nanoparticles (UCNPs) and carbon quantum dots (CQDs) have recently received a lot of attention as promising materials to improve the stability and efficiency of perovskite solar cells (PSCs). This is because they can passivate the surfaces of perovskite-sensitive materials and act as a spectrum converter for sunlight. In this study, we mixed and added both promising nanomaterials to PSC layers at the ideal mixing ratios. When compared to the pristine PSCs, the fabricated PSCs showed improved power conversion efficiency (PCE), from 16.57% to 20.44%, a higher photocurrent, and a superior fill factor (FF), which increased from 70% to 75%. Furthermore, the incorporation of CQDs into the manufactured PSCs shielded the perovskite layer from water contact, producing a device that was more stable than the original.
引用
收藏
页数:12
相关论文
共 37 条
[31]   Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3 [J].
Xing, Guichuan ;
Mathews, Nripan ;
Sun, Shuangyong ;
Lim, Swee Sien ;
Lam, Yeng Ming ;
Graetzel, Michael ;
Mhaisalkar, Subodh ;
Sum, Tze Chien .
SCIENCE, 2013, 342 (6156) :344-347
[32]   High-performance photovoltaic perovskite layers fabricated through intramolecular exchange [J].
Yang, Woon Seok ;
Noh, Jun Hong ;
Jeon, Nam Joong ;
Kim, Young Chan ;
Ryu, Seungchan ;
Seo, Jangwon ;
Seok, Sang Il .
SCIENCE, 2015, 348 (6240) :1234-1237
[33]   Efficient perovskite solar cells via improved carrier management [J].
Yoo, Jason J. ;
Seo, Gabkyung ;
Chua, Matthew R. ;
Park, Tae Gwan ;
Lu, Yongli ;
Rotermund, Fabian ;
Kim, Young-Ki ;
Moon, Chan Su ;
Jeon, Nam Joong ;
Correa-Baena, Juan-Pablo ;
Bulovic, Vladimir ;
Shin, Seong Sik ;
Bawendi, Moungi G. ;
Seo, Jangwon .
NATURE, 2021, 590 (7847) :587-593
[34]   Energy recycling under ambient illumination for internet-of-things using metal/oxide/metal-based colorful organic photovoltaics [J].
You, Young-Jun ;
Saeed, Muhammad Ahsan ;
Shafian, Shafidah ;
Kim, Jisoo ;
Kim, Sang Hyeon ;
Kim, Sung Hyeon ;
Kim, Kyungkon ;
Shim, Jae Won .
NANOTECHNOLOGY, 2021, 32 (46)
[35]   Performance improvement of perovskite solar cells by employing a CdSe quantum dot/PCBM composite as an electron transport layer [J].
Zeng, Xiaofeng ;
Zhou, Tingwei ;
Leng, Chongqian ;
Zang, Zhigang ;
Wang, Ming ;
Hu, Wei ;
Tang, Xiaosheng ;
Lu, Shirong ;
Fang, Liang ;
Zhou, Miao .
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (33) :17499-17505
[36]   Enhanced Power Conversion Efficiency of Perovskite Solar Cells with an Up-Conversion Material of Er3+-Yb3+-Li+ Tri-doped TiO2 [J].
Zhang, Zhenlong ;
Qin, Jianqiang ;
Shi, Wenjia ;
Liu, Yanyan ;
Zhang, Yan ;
Liu, Yuefeng ;
Gao, Huiping ;
Mao, Yanli .
NANOSCALE RESEARCH LETTERS, 2018, 13
[37]   Two-dimensional lead-free hybrid halide perovskite using superatom anions with tunable electronic properties [J].
Zhou, Tingwei ;
Wang, Ming ;
Zang, Zhigang ;
Tang, Xiaosheng ;
Fang, Liang .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2019, 191 :33-38