Coupled mechanical stress and multi-dimensional CFD analysis for high temperature proton exchange membrane fuel cells (HT-PEMFCs)

被引:41
作者
Chippar, Purushothama [1 ]
Oh, Kyeongmin [1 ]
Kim, Dongmin [2 ]
Hong, Tae-Whan [3 ]
Kim, Whangi [4 ]
Ju, Hyunchul [1 ]
机构
[1] Inha Univ, Sch Mech Engn, Inchon 402751, South Korea
[2] Hongik Univ, Dept Mat Sci & Engn, Yeongi 339701, Chungnam, South Korea
[3] Korea Natl Univ Transportat, Dept Mat Sci & Engn, Chungju 380702, Chungbuk, South Korea
[4] Konkuk Univ, Dept Appl Chem, Chungju 380701, Chungbuk, South Korea
基金
新加坡国家研究基金会;
关键词
Proton exchange membrane fuel cell; Polybenzimidazole (PBI); Gas diffusion layer; GDL compression; GDL intrusion; ACID DOPED POLYBENZIMIDAZOLE; GAS-DIFFUSION LAYER; POLYMER ELECTROLYTE; INHOMOGENEOUS COMPRESSION; OXYGEN REDUCTION; MODEL; PERMEABILITY; PERFORMANCE; WATER;
D O I
10.1016/j.ijhydene.2012.07.122
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We use a combined finite element method (FEM)/computational fluid dynamics (CFD) methodology to numerically investigate the effects of gas diffusion layer (GDL) compression/intrusion on the performance of a phosphoric acid-doped polybenzimidazole (PBI) membrane-based high temperature proton exchange membrane fuel cell (HT-PEMFC). Three-dimensional (3-D) FEM simulations are conducted under various displacement clamping conditions to analyze cell deformation characteristics. Then, a multidimensional HT-PEMFC CFD model is applied to the deformed cell geometries to study transport and electrochemical processes during HT-PEMFC operations. Our numerical simulation results reveal that the maximum stresses in the deformed GDLs always occur near the edge of the ribs. The combined effects of GDL compression/intrusion considerably increase spatial non-uniformity in the species and current density distributions, and reduce cell performance. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7715 / 7724
页数:10
相关论文
共 34 条
[1]  
[Anonymous], INT J HEAT MASS TRAN
[2]   Carbon monoxide poisoning of proton exchange membrane fuel cells [J].
Baschuk, JJ ;
Li, XG .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2001, 25 (08) :695-713
[3]   Effect of compression on liquid water transport and microstructure of PEMFC gas diffusion layers [J].
Bazylak, A. ;
Sinton, D. ;
Liu, Z. -S. ;
Djilali, N. .
JOURNAL OF POWER SOURCES, 2007, 163 (02) :784-792
[4]   Mathematical model of a PEMFC using a PBI membrane [J].
Cheddie, D ;
Munroe, N .
ENERGY CONVERSION AND MANAGEMENT, 2006, 47 (11-12) :1490-1504
[5]   A two-phase model of an intermediate temperature PEM fuel cell [J].
Cheddie, Denver F. ;
Munroe, Norman D. H. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (07) :832-841
[6]   Three dimensional modeling of high temperature PEM fuel cells [J].
Cheddie, Denver F. ;
Munroe, Norman D. H. .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :215-223
[7]   On the effects of non-uniform property distribution due to compression in the gas diffusion layer of a PEMFC [J].
Chi, P. H. ;
Chan, S. H. ;
Weng, F. B. ;
Su, Ay ;
Sui, P. C. ;
Djilali, N. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (07) :2936-2948
[8]  
Chippar P, SOLID STATE IN PRESS
[9]   A numerical investigation of the effects of GDL compression and intrusion in polymer electrolyte fuel cells (PEFCs) [J].
Chippar, Purushothama ;
Kyeongmin, O. ;
Kang, Kyungmun ;
Ju, Hyunchul .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2012, 37 (07) :6326-6338
[10]   In-plane and through-plane gas permeability of carbon fiber electrode backing layers [J].
Gostick, Jeff T. ;
Fowler, Michael W. ;
Pritzker, Mark D. ;
Ioannidis, Marios A. ;
Behra, Leya M. .
JOURNAL OF POWER SOURCES, 2006, 162 (01) :228-238