The effect of oxidation on the subsurface microstructure of a Ti-6Al-4V alloy

被引:36
作者
Bagot, P. A. J. [1 ]
Radecka, A. [2 ,3 ]
Magyar, A. P. [4 ]
Gong, Y. [1 ]
Bell, D. C. [4 ]
Smith, G. D. W. [1 ]
Moody, M. P. [1 ]
Dye, D. [2 ]
Rugg, D. [3 ]
机构
[1] Univ Oxford, Dept Mat, Parks Rd, Oxford, England
[2] Imperial Coll, Royal Sch Mines, Dept Mat, Prince Consort Rd, London, England
[3] Rolls Royce PLC, Elton Rd, London, England
[4] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
基金
英国工程与自然科学研究理事会;
关键词
Titanium alloys; Oxidation; Atom probe tomography; alpha-case; ALPHA TITANIUM-ALLOY; MECHANICAL-PROPERTIES; FIELD EVAPORATION; TI ALLOYS; PRECIPITATION; LIFE; ALPHA(2)-TI3AL; DIFFRACTION; PREDICTION; STABILITY;
D O I
10.1016/j.scriptamat.2018.01.015
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Atom Probe Tomography (APT) and Transmission Electron Microscopy (TEM) are combined for examining a case formation in Ti-6Al-4V, generated by air exposure at 800 degrees C. Below the oxide surface, the microstructure separates into a nanoscale mixture of the alpha-Ti and alpha(2) Ti3Al phases, of compositions Ti70-030 and Ti65-010-A120-V5 respectively. The alpha(2) phase exists either as bands or as nanoscale spherical precipitates. Nitrogen also penetrates the surface, but to a lesser extent, while vanadium partitions to alpha(2) or in distinctly separate phases. The results demonstrate that oxygen stimulates precipitation of alpha(2), helping to explain embrittlement produced in the O-enriched layer beneath the oxide. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:24 / 28
页数:5
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