Metal chelate absorption coupled with microbial reduction for the removal of NOx from flue gas

被引:62
作者
Li, W [1 ]
Wu, CZ [1 ]
Shi, Y [1 ]
机构
[1] Zhejiang Univ, Dept Environm Engn, Hangzhou 310027, Peoples R China
关键词
NOx removal; Fe(II)EDTA; microorganisms; absorption; flue gas;
D O I
10.1002/jctb.1394
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
A novel process for the removal of NOx from flue gas by a combined Fe(II)EDTA absorption and microbial reduction has been demonstrated. Fe(II)EDTA-NO and Fe(III)EDTA (EDTA: ethylenediaminetetraacetate) can be effectively reduced to the active Fe(II)EDTA in the reactor containing microorganisms. In a steady-state absorption and regeneration process, the final removal efficiency of NO is up to 88%. The effects of four main parameters (i.e. NOx O-2 and SO2 concentrations, and the amount of cyclic solution) on NOx removal efficiency were experimentally investigated at 50 degrees C. The results provide some insight into conditions required for the successful removal of NOx from flue gas using the approach of Fe(II)EDTA absorption combined with microbial reduction. (c) 2005 Society of Chemical Industry
引用
收藏
页码:306 / 311
页数:6
相关论文
共 17 条
[1]   Environmental processes mediated by iron-reducing bacteria [J].
Fredrickson, JK ;
Gorby, YA .
CURRENT OPINION IN BIOTECHNOLOGY, 1996, 7 (03) :287-294
[2]   SIMULTANEOUS REMOVAL OF NO AND SO2 IN PACKED SCRUBBERS OR SPRAY TOWERS [J].
HARRIOTT, P ;
SMITH, K ;
BENSON, LB .
ENVIRONMENTAL PROGRESS, 1993, 12 (02) :110-113
[3]   Regeneration of nitric oxide chelate absorption solution by two heterotrophic bacterial strains [J].
Jing G.-H. ;
Li W. ;
Shi Y. ;
Ma B.-Y. ;
Tan T.-E. .
Journal of Zhejiang University-SCIENCE A, 2004, 5 (4) :432-435
[4]  
Kieft TL, 1999, APPL ENVIRON MICROB, V65, P1214
[5]   DENITRIFICATION BY THERMOPHILIC SOIL BACTERIA WITH ETHANOL AS SUBSTRATE IN A USB REACTOR [J].
LAURINO, CN ;
SINERIZ, F .
BIOTECHNOLOGY LETTERS, 1991, 13 (04) :299-304
[6]  
[Li Wei 李伟], 2003, [化工学报, Journal of Chemical Industry and Engineering (China)], V54, P1340
[7]   REACTION OF FERROUS CHELATE NITROSYL COMPLEXES WITH SULFITE AND BISULFITE IONS [J].
LITTLEJOHN, D ;
CHANG, SG .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (01) :10-14
[8]   Phylogenetic analysis of dissimilatory Fe(III)-reducing bacteria [J].
Lonergan, DJ ;
Jenter, HL ;
Coates, JD ;
Phillips, EJP ;
Schmidt, TM ;
Lovley, DR .
JOURNAL OF BACTERIOLOGY, 1996, 178 (08) :2402-2408
[9]  
Ma BY, 2004, J ENVIRON SCI-CHINA, V16, P428
[10]   BIOLOGICAL WATER DENITRIFICATION - A REVIEW [J].
MATEJU, V ;
CIZINSKA, S ;
KREJCI, J ;
JANOCH, T .
ENZYME AND MICROBIAL TECHNOLOGY, 1992, 14 (03) :170-183