Differential temperature laser induced fluorescence spectroscopy

被引：3

作者：

Duan, Zicheng

Field, Robert W. ^{[1
]}

Yamakita, Nami

Tsuchiya, Soji

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

[2] George R Harrison Spect Lab, Cambridge, MA 02139 USA

[3] Japan Womens Univ, Fac Sci, Dept Chem & Biol Sci, Bunkyo Ku, Tokyo 1128681, Japan

来源：

CHEMICAL PHYSICS | 2006年 / 324卷 / 2-3期

关键词：

laser induced fluorescence; pattern extraction; vibrational hot bands;

D O I：

10.1016/j.chemphys.2005.12.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We describe a technique, differential temperature laser induced fluorescence (DT-LIF), and an analytical algorithm, structure-based cross correlation (SBCC), that are capable of separating overlapping cold and hot bands in a laser induced fluorescence (LIF) spectrum. DT-LIF/SBCC is illustrated by application to a pair of synthetic spectra, and is demonstrated by application to a segment of an experimental acetylene (A) over tilde-(X) over tilde spectrum. The goal is to identify and separate hot and cold band spectral features numerically, prior to any attempt at assignment of the raw spectrum. The DT-LIF/SBCC combination is shown to be a useful tool for disentangling hot and cold band spectra. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：709 / 720

页数：12

共 12 条

[1] Identifying patterns in multicomponent signals by extended cross correlation [J].