Zwitterionic nido-Carborane-Fused Phospholes

被引：25

作者：

Tao, Guanyu ^{[1
]}

Duan, Zheng ^{[1
]}

Mathey, Francois ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Int Phosphorus Lab, Int Joint Res Lab Funct Organophosphorus Mat Hena, Zhengzhou 450001, Henan, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 07期

基金：

美国国家科学基金会;

关键词：

PHOTOPHYSICAL PROPERTIES; DELAYED FLUORESCENCE; MEDIATED CYCLIZATION; METAL-COMPLEXES; LUMINESCENCE; ANTHRACENE; OXIDES; ROUTE; DYADS; BORON;

D O I：

10.1021/acs.orglett.9b00562

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using readily available and easy-to-handle reagents, a novel type of nido-carborane-fused phosphole was obtained from a simple procedure. Its crystallographic structure was determined, and DFT calculations have been performed, unraveling the key influence of the zwitterionic structure on the photophysical properties.

引用

页码：2273 / 2276

页数：4

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