Zwitterionic nido-Carborane-Fused Phospholes

被引：25

作者：

Tao, Guanyu ^{[1
]}

Duan, Zheng ^{[1
]}

Mathey, Francois ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Int Phosphorus Lab, Int Joint Res Lab Funct Organophosphorus Mat Hena, Zhengzhou 450001, Henan, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 07期

基金：

美国国家科学基金会;

关键词：

PHOTOPHYSICAL PROPERTIES; DELAYED FLUORESCENCE; MEDIATED CYCLIZATION; METAL-COMPLEXES; LUMINESCENCE; ANTHRACENE; OXIDES; ROUTE; DYADS; BORON;

D O I：

10.1021/acs.orglett.9b00562

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using readily available and easy-to-handle reagents, a novel type of nido-carborane-fused phosphole was obtained from a simple procedure. Its crystallographic structure was determined, and DFT calculations have been performed, unraveling the key influence of the zwitterionic structure on the photophysical properties.

引用

页码：2273 / 2276

页数：4

共 63 条

[1] Tuning the Photophysical Properties of Photostable Benzo[b]phosphole P-Oxide-Based Fluorophores [J].

Adler, Raul A. ;

Wang, Chenguang ;

Fukazawa, Aiko ;

Yamaguchi, Shigehiro .

INORGANIC CHEMISTRY, 2017, 56 (15) :8718-8725

[2] Direct Access to -Extended Phosphindolium Salts by Simple Proton-Induced Cyclization of (o-Alkynylphenyl)phosphanes [J].

Arndt, Sebastian ;

Hansmann, Max M. ;

Rominger, Frank ;

Rudolph, Matthias ;

Hashmi, A. Stephen K. .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (23) :5429-5433

[3] Intramolecular anti-Phosphinoauration of Alkynes: An FLP-Motivated Approach to Stable Aurated Phosphindolium Complexes [J].

Arndt, Sebastian ;

Hansmann, Max M. ;

Motloch, Petr ;

Rudolph, Matthias ;

Rominger, Frank ;

Hashmi, A. Stephen K. .

CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (11) :2542-2547

[4] Phospholyl(borane) Amino Acids and Peptides: Stereoselective Synthesis and Fluorescent Properties with Large Stokes Shift [J].

Arribat, Mathieu ;

Remond, Emmanuelle ;

Clement, Sebastien ;

Van Der Lee, Arie ;

Cavelier, Florine .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (03) :1028-1034

[5] Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinating nido-Carborane-Based Ligands [J].

Axtell, Jonathan C. ;

Kirlikovali, Kent O. ;

Djurovich, Peter I. ;

Jung, Dahee ;

Nguyen, Vinh T. ;

Munekiyo, Brian ;

Royappa, A. Timothy ;

Rheingold, Arnold L. ;

Spokoyny, Alexander M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (48) :15758-15765

[6]

BIAN DQ, 2013, CHINESE J ORG CHEM, V33, P1774, DOI DOI 10.6023/CJOC201302007

[7] Silver-Mediated Oxidative C-H/P-H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides [J].

Chen, Yun-Rong ;

Duan, Wei-Liang .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (45) :16754-16757

[8] KNOWLEDGE OF ORGANOPHOSPHORUS COMPOUNDS .23. ALKENYL SUBSTITUTED AMINOPHOSPHANES AND HALOGENOPHOSPHANES AND EXPERIMENTS ON INTRAMOLECULAR PHOSPHINIDENE OBSERVATION [J].

DIEMERT, K ;

KOTTWITZ, B ;

KUCHEN, W .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1986, 26 (03) :307-320

[9] Synthesis and crystal structure of three carborane complexes, [M{7,8-(OPPh2)2-7,8-C2B9H10}2] (M = Cu, Zn) and [Ni(thf){7,8-(OPPh2)2-7,8-C2B9H10}2]•thf and two carborane compounds, 1-(OPPh2)-2-(PPh2)-1,2-C2B10H10 and H[7,8-(OPPh2)2-7,8-C2B9H10]-0.25C2H5OH [J].

Dou, Jianmin ;

Zhang, Daopeng ;

Li, Dacheng ;

Wang, Daqi .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, (01) :53-59

[10] Tumor Targeting, Trifunctional Dendritic Wedge [J].

Dubey, Ramin ;

Kushal, Swati ;

Mollard, Alexis ;

Vojtovich, Lesya ;

Oh, Philip ;

Levin, Michael D. ;

Schnitzer, Jan E. ;

Zharov, Ilya ;

Olenyuk, Bogdan Z. .

BIOCONJUGATE CHEMISTRY, 2015, 26 (01) :78-89

← 1 2 3 4 5 6 7 →