Ring opening polymerization of 2-aminothiazole with iron(III) chloride

被引：14

作者：

Ciftci, Hakan ^{[1
]}

Testereci, Hasan Nur ^{[2
]}

Oktem, Zeki ^{[2
]}

机构：

[1] Kirikkale Univ, Kirikkale Vocat High Sch, Dept Chem & Chem Proc Technol, TR-71100 Yahsihan, Kirikkale, Turkey

[2] Kirikkale Univ, Fac Art & Sci, Dept Chem, TR-71100 Yahsihan, Kirikkale, Turkey

来源：

POLYMER BULLETIN | 2013年 / 70卷 / 06期

关键词：

Poly(2-aminothiazole); Iron(III) chloride; Chemical polymerization; Conducting polymer; Ring opening; AQUEOUS-MEDIUM; THIAZOLE; POLYMERS; PRECONCENTRATION; POLYTHIAZOLES; FAAS; NI; CU;

D O I：

10.1007/s00289-012-0886-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2-aminothiazole), PAT, was synthesized by the chemical polymerization of 2-aminothiazole, AT, with FeCl3 center dot 6H(2)O in 1,4-dioxane. The effect of temperature, monomer, and initiator concentration and polymerization time on the rate of polymerization was studied. The structural analysis of the polymer was carried out by elemental analysis and H-1-NMR, FTIR, and UV-VIS spectroscopies. Thermal properties were studied by DSC and TGA. Conductivity measurements were carried out by four-probe technique and the number average molecular weight, M (n), of the polymer was determined by cryoscopy.

引用

页码：1895 / 1909

页数：15

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