Recovery from applied strain in interpenetrating polymer network hydrogels with ionic and covalent cross-links

被引:132
作者
Bakarich, Shannon E. [1 ]
Pidcock, Geoffrey C. [1 ]
Balding, Paul [1 ]
Stevens, Leo [1 ]
Calvert, Paul [2 ]
Panhuis, Marc In Het [1 ,3 ]
机构
[1] Univ Wollongong, Soft Mat Grp, Sch Chem, Wollongong, NSW 2522, Australia
[2] Univ Massachusetts Dartmouth, Dept Bioengn, N Dartmouth, MA 02747 USA
[3] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia
基金
澳大利亚研究理事会;
关键词
GELLAN GUM; HYSTERESIS; GELATION;
D O I
10.1039/c2sm26745d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have prepared an interpenetrating polymer network hydrogel based on the simultaneous formation of two polymer networks, gellan gum and poly(acrylamide). The gellan gum network is ionically cross-linked, while poly(acrylamide) network is covalently cross-linked. These gels can recover 53 +/- 4% of the hysteresis of the first compressive cycle and 90 +/- 9% of subsequent cycles.
引用
收藏
页码:9985 / 9988
页数:4
相关论文
共 22 条
[1]   Hydrogels for Soft Machines [J].
Calvert, Paul .
ADVANCED MATERIALS, 2009, 21 (07) :743-756
[2]   Modified Gellan Gum hydrogels with tunable physical and mechanical properties [J].
Coutinho, Daniela F. ;
Sant, Shilpa V. ;
Shin, Hyeongho ;
Oliveira, Joao T. ;
Gomes, Manuela E. ;
Neves, Nuno M. ;
Khademhosseini, Ali ;
Reis, Rui L. .
BIOMATERIALS, 2010, 31 (29) :7494-7502
[3]   Growth Factors, Matrices, and Forces Combine and Control Stem Cells [J].
Discher, Dennis E. ;
Mooney, David J. ;
Zandstra, Peter W. .
SCIENCE, 2009, 324 (5935) :1673-1677
[4]   Conducting bio-materials based on gellan gum hydrogels [J].
Ferris, Cameron John ;
Panhuis, Marc In Het .
SOFT MATTER, 2009, 5 (18) :3430-3437
[5]   Occurrence, production, and applications of gellan:: current state and perspectives [J].
Fialho, Arsenio M. ;
Moreira, Leonilde M. ;
Granja, Ana Teresa ;
Popescu, Alma O. ;
Hoffmann, Karen ;
Sa-Correia, Isabel .
APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2008, 79 (06) :889-900
[6]   Gellan gum [J].
Giavasis, I ;
Harvey, LM ;
McNeil, B .
CRITICAL REVIEWS IN BIOTECHNOLOGY, 2000, 20 (03) :177-211
[7]   Why are double network hydrogels so tough? [J].
Gong, Jian Ping .
SOFT MATTER, 2010, 6 (12) :2583-2590
[8]   Double-network hydrogels with extremely high mechanical strength [J].
Gong, JP ;
Katsuyama, Y ;
Kurokawa, T ;
Osada, Y .
ADVANCED MATERIALS, 2003, 15 (14) :1155-+
[9]   GELATION OF GELLAN GUM [J].
GRASDALEN, H ;
SMIDSROD, O .
CARBOHYDRATE POLYMERS, 1987, 7 (05) :371-393
[10]   Lamellar Bilayers as Reversible Sacrificial Bonds To Toughen Hydrogel: Hysteresis, Self-Recovery, Fatigue Resistance, and Crack Blunting [J].
Haque, M. Anamul ;
Kurokawa, Takayuki ;
Kamita, Gen ;
Gong, J. Ping .
MACROMOLECULES, 2011, 44 (22) :8916-8924