From classical to nonclassical metal-boron bonds: Synthesis of a novel metallaborane

被引：0

作者：

Braunschweig, H ^{[1
]}

Colling, M

Hu, CH

Radacki, K

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 08期

关键词：

D O I：

10.1002/1521-3773(20020415)41:8<1359::AID-ANIE1359>3.0.CO;2-J

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Boron, butterflies, and the missing link: The first synthetic link between electron-precise borylene complexes such as 1 and electron-deficient metallaboranes is achieved with the preparation of 2. This result introduces two novel features to the chemistry of the metallaboranes - unbridged B2Hal2 moieties (Hal = halogen) as cluster fragments and the four vertex nido-"butterfly" as a structural motif.

引用

页码：1359 / 1361

页数：3

共 42 条

[1] REACTIONS OF METAL-TO-METAL MULTIPLE BONDS .4. MU-ACETYLENE-BIS(CYCLOPENTADIENYL)TETRACARBONYLDIMOLYBDENUM COMPOUNDS - PREPARATIONS, PROPERTIES, STRUCTURAL CHARACTERIZATIONS, AND DYNAMICAL SOLUTION BEHAVIOR
BAILEY, WI
CHISHOLM, MH
COTTON, FA
RANKEL, LA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (18) : 5764 - 5773
[2] Braunschweig H, 1998, ANGEW CHEM INT EDIT, V37, P1786, DOI 10.1002/(SICI)1521-3773(19980803)37:13/14<1786::AID-ANIE1786>3.0.CO
[3] 2-C
[4] Transition metal complexes of boron - synthesis, structure and reactivity
Braunschweig, H
Colling, M
[J]. COORDINATION CHEMISTRY REVIEWS, 2001, 223 : 1 - 51
[5] Braunschweig H, 1998, ANGEW CHEM INT EDIT, V37, P3179, DOI 10.1002/(SICI)1521-3773(19981204)37:22<3179::AID-ANIE3179>3.0.CO
[6] 2-Z
[7] Braunschweig H, 2002, INORGANIC CHEMISTRY HIGHLIGHTS, P213
[8] Braunschweig H, 2001, ANGEW CHEM INT EDIT, V40, P4198, DOI 10.1002/1521-3773(20011119)40:22<4198::AID-ANIE4198>3.0.CO
[9] 2-E
[10] Braunschweig H, 2001, ANGEW CHEM INT EDIT, V40, P2298, DOI 10.1002/1521-3773(20010618)40:12<2298::AID-ANIE2298>3.0.CO

← 1 2 3 4 5 →