Characterization of nineteen antimony(III) complexes as potent inhibitors of photosystem II, carbonic anhydrase, and glutathione reductase

被引：15

作者：

Karacan, Mehmet Sayim ^{[1
]}

Rodionova, Margarita V. ^{[2
]}

Tunc, Turgay ^{[3
]}

Venedik, Kubra Begum ^{[1
]}

Mamas, Serhat ^{[1
]}

Shitov, Alexandr V. ^{[4
]}

Zharmukhamedov, Sergei K. ^{[4
]}

Klimov, Vyacheslav V. ^{[4
]}

Karacan, Nurcan ^{[1
]}

Allakhverdiev, Suleyman I. ^{[2
,4
,5
]}

机构：

[1] Gazi Univ, Fac Sci, Dept Chem, Ankara, Turkey

[2] Russian Acad Sci, Inst Plant Physiol, Controlled Photobiosynth Lab, Bot Skaya St 35, Moscow 127276, Russia

[3] Ahi Evran Univ, Dept Chem & Proc Engn, Fac Engn & Architecture, Kirsehir, Turkey

[4] Russian Acad Sci, Inst Basic Biol Problems, Inst Skaya St 2, Pushchino 142290, Moscow Region, Russia

[5] Moscow MV Lomonosov State Univ, Fac Biol, Dept Plant Physiol, Leninskie Gory 1-12, Moscow 119991, Russia

来源：

PHOTOSYNTHESIS RESEARCH | 2016年 / 130卷 / 1-3期

基金：

俄罗斯基础研究基金会;

关键词：

Photosystem II (PSII); Carbonic anhydrase; Glutathione reductase; Antimony(III) complexes; Inhibitors; CHLAMYDOMONAS-REINHARDTII; ANTIBACTERIAL ACTIVITY; ANTIMICROBIAL ACTIVITY; ELECTRON-TRANSFER; PEA THYLAKOIDS; DERIVATIVES; MEMBRANE; NICKEL(II); BIOSYNTHESIS; CHLOROPLASTS;

D O I：

10.1007/s11120-016-0236-z

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

Nineteen antimony(III) complexes were obtained and examined as possible herbicides. Six of these were synthesized for the first time, and their structures were identified using elemental analyses, H-1-NMR, C-13-NMR, FTIR, LCMS, magnetic susceptibility, and conductivity measurement techniques. For the nineteen examined antimony(III) complexes their most-stable forms were determined by DFT/B3LYP/LanL2DZ calculation method. These compounds were examined for effects on photosynthetic electron transfer and carbonic anhydrase activity of photosystem II, and glutathione reductase from chloroplast as well were investigated. Our results indicated that all antimony(III) complexes inhibited glutathione reductase activity of chloroplast. A number of these also exhibited good inhibitory efficiency of the photosynthetic and carbonic anhydrase activity of Photosystem II.

引用

页码：167 / 182

页数：16

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