Synthesis of flower-like ZnO microstructures for gas sensor applications

被引:142
作者
Rai, Prabhakar
Raj, Sudarsan
Ko, Kyoung-Jun
Park, Kyung-Keun
Yu, Yeon-Tae [1 ]
机构
[1] Chonbuk Natl Univ, Coll Engn, Div Adv Mat Engn, Jeonju 561756, South Korea
基金
新加坡国家研究基金会;
关键词
ZnO; Gas sensor; CO; Ethanol; Acetaldehyde; NO2; NANOSTRUCTURES; NANORODS; NO2;
D O I
10.1016/j.snb.2012.12.031
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the present work, flower-like ZnO microstructures were used for solid state gas sensor applications. Well-dispersed flower-like ZnO microstructures were synthesized by hydrothermal method. The size of flower-like ZnO microstructures was about 5-7 mu m in radius and they were made up of dozen of ZnO nanorods building block units. Gas sensing device was prepared by thick film technology and tested primarily for NO2 gas at different testing temperatures as well as concentrations. Response increased with gas concentration as well as temperature (except 400 degrees C). Further, it showed response for 10 ppm of NO2 gas at room temperature. The response for NO2 was higher than the CO, ethanol and acetaldehyde at low operating temperatures. These flower-like ZnO microstructures showed some sort of selectivity for NO2 below 300 degrees C. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:107 / 112
页数:6
相关论文
共 26 条
[1]   Different morphologies of ZnO nanorods and their sensing property [J].
Bai Shouli ;
Chen Liangyuan ;
Li Dianqing ;
Yang Wensheng ;
Yang Pengcheng ;
Liu Zhiyong ;
Chen Aifan ;
Chung Chiun Liu .
SENSORS AND ACTUATORS B-CHEMICAL, 2010, 146 (01) :129-137
[2]  
DEVI GS, 1995, SENSOR ACTUAT B-CHEM, V28, P31, DOI 10.1016/0925-4005(94)01535-P
[3]  
Environmental Protection Agency (EPA), 2011, AIR POLLUTION
[4]  
European Environment Agency (EEA), 2010, EUR EXC AIR POLL EM
[5]   Contact-controlled sensing properties of flowerlike ZnO nanostructures [J].
Feng, P ;
Wan, Q ;
Wang, TH .
APPLIED PHYSICS LETTERS, 2005, 87 (21) :1-3
[6]   On the role of individual metal oxide nanowires in the scaling down of chemical sensors [J].
Hernandez-Ramirez, Francisco ;
Prades, J. Daniel ;
Jimenez-Diaz, Roman ;
Fischer, Thomas ;
Romano-Rodriguez, Albert ;
Mathur, Sanjay ;
Morante, Joan R. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (33) :7105-7110
[7]   Necked ZnO nanoparticle-based NO2 sensors with high and fast response [J].
Jun, Jin Hyung ;
Yun, Junggwon ;
Cho, Kyoungah ;
Hwang, In-Sung ;
Lee, Jong-Heun ;
Kim, Sangsig .
SENSORS AND ACTUATORS B-CHEMICAL, 2009, 140 (02) :412-417
[8]   NITRIC OXIDE AIR POLLUTION - DETECTION BY OPTOACOUSTIC SPECTROSCOPY [J].
KREUZER, LB ;
PATEL, CKN .
SCIENCE, 1971, 173 (3991) :45-&
[9]   Highly sensitive semiconductor NOx gas sensor operating at room temperature [J].
Kunimoto, A ;
Abe, N ;
Uchida, H ;
Katsube, T .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 65 (1-3) :122-124
[10]   Different origins of visible luminescence in ZnO nanostructures fabricated by the chemical and evaporation methods [J].
Li, D ;
Leung, YH ;
Djurisic, AB ;
Liu, ZT ;
Xie, MH ;
Shi, SL ;
Xu, SJ ;
Chan, WK .
APPLIED PHYSICS LETTERS, 2004, 85 (09) :1601-1603