Diphenylphosphanylsulfoximines as ligands in iridium-catalyzed asymmetric imine hydrogenations

被引：171

作者：

Moessner, C ^{[1
]}

Bolm, C ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 46期

关键词：

amines; asymmetric catalysis; hydrogenation; imines; sulfoximines;

D O I：

10.1002/anie.200502482

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Easily accessible phosphine-substituted sulfoximines 2 have been applied in Ir-catalyzed asymmetric hydrogenations of acylic N-arylated imines 1. The amines 3 are formed under mild conditions in high yields with excellent ee values. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7564 / 7567

页数：4

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