Bottom-up Synthesis of Nanoscale Conjugation-Interrupted Frameworks and Their Electrical Properties

被引：16

作者：

Chang, Yong-Zheng ^{[1
,2
]}

Shao, Qi ^{[3
]}

Bai, Lin-Yi ^{[1
,2
]}

Ou, Chang-Jin ^{[1
,2
]}

Lin, Jin-Yi ^{[1
,2
]}

Xie, Ling-Hai ^{[1
,2
]}

Liu, Zheng-Dong ^{[1
,2
]}

Chen, Xiaodong ^{[3
]}

Zhang, Guang-Wei ^{[1
,2
]}

Huang, Wei ^{[1
,2
]}

机构：

[1] Nanjing Univ Posts & Telecommun, CMSOD, KLOEID, Nanjing 210046, Jiangsu, Peoples R China

[2] Nanjing Univ Posts & Telecommun, IAM, Nanjing 210046, Jiangsu, Peoples R China

[3] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

来源：

SMALL | 2013年 / 9卷 / 19期

关键词：

dendrimers; electrical properties; organic nanostructures; synthetic methods; thin films; H BOND ACTIVATION; TRANSPORT JUNCTIONS; POLYPHENYLENE DENDRIMERS; EMITTING DENDRIMERS; CONDUCTIVITY; CHEMISTRY; DENDRONS; POLYMER; MACROMOLECULES; SEMICONDUCTORS;

D O I：

10.1002/smll.201300065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Soluble covalent organic nanoframeworks up to generation 2.5 (G2.5) are synthesized with self-similar H-shaped conformations by using a bottom-up approach including iterative C-H bond functionalization. The electrical characteristics of nanoscale thin-film semiconductors of the conjugation-interrupted frameworks can be tuned by post-modification with diazonium salt. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3218 / 3223

页数：6

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