Iodo-BODIPY: a visible-light-driven, highly efficient and photostable metal-free organic photocatalyst

被引：102

作者：

Li, Wenliang ^{[1
,3
]}

Li, Leijiao ^{[2
]}

Xiao, Haihua ^{[1
]}

Qi, Ruogu ^{[1
]}

Huang, Yubin ^{[1
]}

Xie, Zhigang ^{[1
]}

Jing, Xiabin ^{[1
]}

Zhang, Hongxing ^{[2
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Jilin Univ, Inst Theoret Chem, State Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China

[3] Jilin Med Coll, Changchun 132013, Jilin, Peoples R China

来源：

RSC ADVANCES | 2013年 / 3卷 / 32期

基金：

中国国家自然科学基金;

关键词：

SINGLET-OXYGEN; EXCITED-STATES; OXIDATION; FLUORESCENT; DERIVATIVES; DYES; PHOTOSENSITIZERS; GENERATION; SULFIDES; 1,3-DIPHENYLISOBENZOFURAN;

D O I：

10.1039/c3ra40932e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Boron-dipyrromethene (BODIPY) compounds have been used extensively. However, their application in photocatalysis has not been well-studied. In this report, iodo-BODIPYs were utilized as visible-light-driven photocatalysts. They demonstrated very high catalytic efficiencies and reaction rates for the photocatalyzed oxidation of thioanisole under visible light.

引用

页码：13417 / 13421

页数：5

共 49 条

[11]

Brustad E., 2008, ANGEW CHEMIE, V120, P8344

[12] Designing Excited States: Theory-Guided Access to Efficient Photosensitizers for Photodynamic Action [J].

Cakmak, Yusuf ;

Kolemen, Safacan ;

Duman, Selin ;

Dede, Yavuz ;

Dolen, Yusuf ;

Kilic, Bilal ;

Kostereli, Ziya ;

Yildirim, Leyla Tatar ;

Dogan, A. Lale ;

Guc, Dicle ;

Akkaya, Engin U. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (50) :11937-11941

[13] Phenylethynyl-BODIPY Oligomers: Bright Dyes and Fluorescent Building Blocks [J].

Cakmak, Yusuf ;

Akkaya, Engin U. .

ORGANIC LETTERS, 2009, 11 (01) :85-88

[14] ON THE USE OF 1,3-DIPHENYLISOBENZOFURAN (DPBF) - REACTIONS WITH CARBON AND OXYGEN-CENTERED RADICALS IN MODEL AND NATURAL SYSTEMS [J].

CARLONI, P ;

DAMIANI, E ;

GRECI, L ;

STIPA, P ;

TANFANI, F ;

TARTAGLINI, E ;

WOZNIAK, M .

RESEARCH ON CHEMICAL INTERMEDIATES, 1993, 19 (05) :395-405

[15] Persulfoxide: Key intermediate in reactions of singlet oxygen with sulfides [J].

Clennan, EL .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (11) :875-884

[16] STUDY OF PEROXIDATION OF ORGANIC COMPOUNDS BY EXTERNALLY GENERATED SINGLET OXYGEN MOLECULES [J].

COREY, EJ ;

TAYLOR, WC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (18) :3881-&

[17]

Dav J., 2012, CHEMCATCHEM, V4, P620

[18] Enzymatic synthesis of biodiesel from fatty acids. Kinetics of the reaction measured by fluorescent response of Nile Red [J].

Fedosov, Sergey N. ;

Xu, Xuebing .

BIOCHEMICAL ENGINEERING JOURNAL, 2011, 56 (03) :172-183

[19] SINGLET OXYGEN . PROBABLE INTERMEDIATE IN PHOTOSENSITIZED AUTOXIDATIONS [J].

FOOTE, CS ;

WEXLER, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (18) :3880-&

[20]

HAY PJ, 1985, J CHEM PHYS, V82, P299, DOI [10.1063/1.448800, 10.1063/1.448799]

← 1 2 3 4 5 →