Iodo-BODIPY: a visible-light-driven, highly efficient and photostable metal-free organic photocatalyst

被引：101
作者：
Li, Wenliang [1 ,3 ]
Li, Leijiao [2 ]
Xiao, Haihua [1 ]
Qi, Ruogu [1 ]
Huang, Yubin [1 ]
Xie, Zhigang [1 ]
Jing, Xiabin [1 ]
Zhang, Hongxing [2 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Jilin Univ, Inst Theoret Chem, State Key Lab Theoret & Computat Chem, Changchun 130023, Peoples R China
[3] Jilin Med Coll, Changchun 132013, Jilin, Peoples R China
来源：
RSC ADVANCES | 2013年 / 3卷 / 32期
基金：
中国国家自然科学基金;
关键词：
SINGLET-OXYGEN; EXCITED-STATES; OXIDATION; FLUORESCENT; DERIVATIVES; DYES; PHOTOSENSITIZERS; GENERATION; SULFIDES; 1,3-DIPHENYLISOBENZOFURAN;
D O I：
10.1039/c3ra40932e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Boron-dipyrromethene (BODIPY) compounds have been used extensively. However, their application in photocatalysis has not been well-studied. In this report, iodo-BODIPYs were utilized as visible-light-driven photocatalysts. They demonstrated very high catalytic efficiencies and reaction rates for the photocatalyzed oxidation of thioanisole under visible light.
引用
收藏
页码：13417 / 13421
页数：5
相关论文
共 49 条
[1]   Toward reliable density functional methods without adjustable parameters: The PBE0 model [J].
Adamo, C ;
Barone, V .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (13) :6158-6170
[2]   Aza-BODIPY Derivatives: Enhanced Quantum Yields of Triplet Excited States and the Generation of Singlet Oxygen and their Role as Facile Sustainable Photooxygenation Catalysts [J].
Adarsh, Nagappanpillai ;
Shanmugasundaram, Madhesh ;
Avirah, Rekha R. ;
Ramaiah, Danaboyina .
CHEMISTRY-A EUROPEAN JOURNAL, 2012, 18 (40) :12655-12662
[3]   Tuning Photosensitized Singlet Oxygen Generation Efficiency of Novel Aza-BODIPY Dyes [J].
Adarsh, Nagappanpillai ;
Avirah, Rekha R. ;
Ramaiah, Danaboyina .
ORGANIC LETTERS, 2010, 12 (24) :5720-5723
[4]   Probes and polymers for optical sensing of oxygen [J].
Amao, Y .
MICROCHIMICA ACTA, 2003, 143 (01) :1-12
[5]   Selective Hg(II) Sensing with Improved Stokes Shift by Coupling the Internal Charge Transfer Process to Excitation Energy Transfer [J].
Atilgan, Serdar ;
Ozdemir, Tugba ;
Akkaya, Engin U. .
ORGANIC LETTERS, 2010, 12 (21) :4792-4795
[6]   Fluorescent indicators based on BODIPY [J].
Boens, Noel ;
Leen, Volker ;
Dehaen, Wim .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (03) :1130-1172
[7]   Photocatalytic oxidation of aliphatic and aromatic sulfides in the presence of silica adsorbed or zeolite-encapsulated 2,4,6-triphenyl(thia)pyrylium [J].
Bonesi, Sergio M. ;
Carbonell, Esther ;
Garcia, Hermenegildo ;
Fagnoni, Maurizio ;
Albini, Angelo .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 79 (04) :368-375
[8]   Photosensitized oxidation of sulfides: Discriminating between the singlet-oxygen mechanism and electron transfer involving superoxide anion or molecular oxygen [J].
Bonesi, Sergio M. ;
Manet, Ilse ;
Freccero, Mauro ;
Fagnoni, Maurizio ;
Albini, Angelo .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (18) :4844-4857
[9]   Photosensitized oxidation of phenyl and tert-butyl sulfides [J].
Bonesi, SM ;
Fagnoni, M ;
Monti, S ;
Albini, A .
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2004, 3 (05) :489-493
[10]   Glossary of terms used in Photochemistry 3rd Edition (IUPAC Recommendations 2006) [J].
Braslavsky, S. E. .
PURE AND APPLIED CHEMISTRY, 2007, 79 (03) :293-465
12345