Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones

被引：392

作者：

Lu, Qingquan ^{[1
]}

Zhang, Jian ^{[1
]}

Wei, Fuliang ^{[3
]}

Qi, Yue ^{[1
]}

Wang, Huamin ^{[1
]}

Liu, Zhiliang ^{[1
]}

Lei, Aiwen ^{[1
,2
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

[2] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

[3] Nanjing Univ Posts & Telecommun, Sch Mat Sci & Engn, Nanjing, Jiangsu, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 28期

基金：

中国国家自然科学基金;

关键词：

alkenes; dioxygen activation; oxidative difunctionalization; sulfinic acids; -hydroxysulfones; BAKERS-YEAST REDUCTION; MOLECULAR-OXYGEN; KETO-SULFONES; METAL-FREE; CATALYZED OXIDATION; DIOXYGEN ACTIVATION; UNSATURATED-HYDROCARBONS; CONVENIENT SYNTHESIS; CARBONYL-COMPOUNDS; HYDROXY SULFONES;

D O I：

10.1002/anie.201301634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New channel! A novel and attractive dioxygen activation by sulfinic acids was explored that is capable of performing efficiently without the assistance of transition metals or radical initiators. This reaction furnishes secondary and tertiary β-hydroxysulfones under mild conditions; β-hydroperoxysulfone was isolated as an important intermediate. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7156 / 7159

页数：4

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