Surfactant-free Synthesis and Formation Mechanism of Fe3O4 Nanospheres in Mixed Solvent Ethylene Glycol-Water System

被引:4
作者
Xu, Yanyan [1 ]
Cao, Yanyan [1 ]
Sun, Yaqiu [1 ]
Zhang, Guoying [1 ]
Gao, Dongzhao [1 ]
机构
[1] Tianjin Normal Univ, Sch Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
IRON-OXIDE; BIOLOGICAL APPLICATIONS; ION BATTERIES; NANOPARTICLES; MICROSPHERES; NANORODS; NANOCRYSTALS; NANOSHEETS; SALTS;
D O I
10.1246/cl.2012.686
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniform Fe3O4 nanospheres have been synthesized by a simple ethylene glycol-H2O system without adding any additives. The average diameter of the Fe3O4 nanospheres was 120-190 nm, and the nanospheres are formed by nanoparticles of several tens of nanometers. The presence of a certain amount of deionized water and the controlled reaction temperature plays an important role in the formation of the Fe3O4 nanospheres. The formation mechanism of the nanospheres is discussed on the basis of the experimental results.
引用
收藏
页码:686 / 688
页数:3
相关论文
共 23 条
[1]   L-Serine-Assisted Synthesis of Superparamagnetic Fe3O4 Nanocubes for Lithuium Ion Batteries [J].
Cao, Huaqiang ;
Liang, Renlong ;
Qian, Dong ;
Shao, Jin ;
Qu, Meizhen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (50) :24688-24695
[2]   Fe3O4 polyhedral nanoparticles with a high magnetization synthesized in mixed solvent ethylene glycol-water system [J].
Cao, Shao-Wen ;
Zhu, Ying-Jie ;
Chang, Jiang .
NEW JOURNAL OF CHEMISTRY, 2008, 32 (09) :1526-1530
[3]   Controlled synthesis of Fe3O4 nanosheets via one-step pyrolysis of EDTA ferric sodium salt [J].
Chen, Lingyun ;
Zhao, Chenglan ;
Zhou, Yang ;
Peng, Hui ;
Zheng, Yiyang .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 504 (02) :L46-L50
[4]   Tunable synthesis of carboxyl-functionalized magnetite nanocrystal clusters with uniform size [J].
Cheng, Changming ;
Wen, Yinghui ;
Xu, Xuefei ;
Gu, Hongchen .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (46) :8782-8788
[5]   Large-scale synthesis of Fe3O4 nanosheets at low temperature [J].
Chin, Kok Chung ;
Chong, Ghee Lee ;
Poh, Chee Kok ;
Van, Li Hui ;
Sow, Chorng Haur ;
Lin, Jianyi ;
Wee, Andrew Thye Shen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (26) :9136-9141
[6]   Monodisperse magnetic single-crystal ferrite microspheres [J].
Deng, H ;
Li, XL ;
Peng, Q ;
Wang, X ;
Chen, JP ;
Li, YD .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (18) :2782-2785
[7]   Superparamagnetic magnetite colloidal nanocrystal clusters [J].
Ge, Jianping ;
Hu, Yongxing ;
Biasini, Maurizio ;
Beyermann, Ward P. ;
Yin, Yadong .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (23) :4342-4345
[8]   Synthesis, Functionalization, and Biomedical Applications of Multifunctional Magnetic Nanoparticles [J].
Hao, Rui ;
Xing, Ruijun ;
Xu, Zhichuan ;
Hou, Yanglong ;
Gao, Song ;
Sun, Shouheng .
ADVANCED MATERIALS, 2010, 22 (25) :2729-2742
[9]   Synthesis and characterization of functionalized silica-coated Fe3O4 superparamagnetic nanocrystals for biological applications [J].
He, YP ;
Wang, SQ ;
Li, CR ;
Miao, YM ;
Wu, ZY ;
Zou, BS .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (09) :1342-1350
[10]   Environmentally-friendly preparation of water-dispersible magnetite nanoparticles [J].
Jia, Xiao ;
Chen, Dairong ;
Jiao, Xiuling ;
Zhai, Shumei .
CHEMICAL COMMUNICATIONS, 2009, (08) :968-970