Insertion of Zerovalent Nickel into the N-N Bond of N-Heterocyclic-Carbene-Activated N2O

被引：27

作者：

Tskhovrebov, Alexander G. ^{[1
]}

Solari, Euro ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 20期

基金：

瑞士国家科学基金会;

关键词：

OXYGEN-ATOM TRANSFER; ORGANIC NITROSO-COMPOUNDS; STRUCTURAL-CHARACTERIZATION; REDUCTIVE CLEAVAGE; DINITROGEN OXIDE; CARBON-MONOXIDE; METAL CENTERS; COMPLEXES; AMIDO; REACTIVITY;

D O I：

10.1021/ic401524w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-mediated cleavage of the N-N bond is a rarely observed phenomenon in the chemistry of nitrous oxide (N2O). We demonstrate that, upon activation of N2O with N-heterocyclic carbenes, zerovalent nickel is able to insert into the N-N bond to give nitrosyl complexes.

引用

页码：11688 / 11690

页数：3

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