Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes: coupling of Ti=NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP

被引：35

作者：

Selby, Jonathan D. ^{[3
]}

Schulten, Christian ^{[2
]}

Schwarz, Andrew D. ^{[3
]}

Stasch, Andreas ^{[2
]}

Clot, Eric ^{[1
]}

Jones, Cameron ^{[2
]}

Mountford, Philip ^{[3
]}

机构：

[1] UM2, CNRS, ENSCM,UM1cc 1501, Inst Charles Gerhardt Montpellier,UMR 5253, F-34095 Montpellier 5, France

[2] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[3] Univ Oxford, Chem Res Lab, Oxford OX1 3TA, England

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 41期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b813911c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first structurally authenticated [2+2] cycloaddition products of any transition metal hydrazide complexes are reported; cycloaddition products of transition metal hydrazides with alkynes and heteroalkynes have been obtained for the first time; these are the first structurally authenticated cycloaddition products for any transition metal M = NNR2 functional group.

引用

页码：5101 / 5103

页数：3

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