Temperature-controlled phase-transfer catalysis for ethylene glycol production from cellulose

被引：147

作者：

Tai, Zhijun ^{[1
,2
]}

Zhang, Junying ^{[1
,2
]}

Wang, Aiqin ^{[1
]}

Zheng, Mingyuan ^{[1
]}

Zhang, Tao ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 56期

基金：

美国国家科学基金会;

关键词：

TUNGSTEN CARBIDE CATALYSTS; RETRO-ALDOL CONDENSATION; 1,2-PROPYLENE GLYCOL; BIMETALLIC CATALYSTS; SUPERCRITICAL WATER; CONVERSION; CELLOBIOSE; SORBITOL; OXIDE;

D O I：

10.1039/c2cc32305b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A temperature-controlled phase-transfer catalyst-tungsten acid, which in combination with a robust heterogeneous catalyst Ru/C shows a high activity and exceptional reusability for the one-pot conversion of cellulose to ethylene glycol. This binary system can be reused more than 20 times with ethylene glycol yield over 50%.

引用

页码：7052 / 7054

页数：3

共 23 条

[1] CHEMISTRY OF TUNGSTEN-OXIDE BRONZES [J].

BARTHA, L ;

KISS, AB ;

SZALAY, T .

INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 1995, 13 (1-3) :77-91

[2] Acid-catalysed direct transformation of cellulose into methyl glucosides in methanol at moderate temperatures [J].

Deng, Weiping ;

Liu, Mi ;

Zhang, Qinghong ;

Tan, Xuesong ;

Wang, Ye .

CHEMICAL COMMUNICATIONS, 2010, 46 (15) :2668-2670

[3] Selective Transformation of Cellulose into Sorbitol by Using a Bifunctional Nickel Phosphide Catalyst [J].

Ding, Li-Ning ;

Wang, Ai-Qin ;

Zheng, Ming-Yuan ;

Zhang, Tao .

CHEMSUSCHEM, 2010, 3 (07) :818-821

[4] Catalytic conversion of cellulose into sugar alcohols [J].

Fukuoka, Atsushi ;

Dhepe, Paresh L. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (31) :5161-5163

[5] Efficient hydrolytic hydrogenation of cellulose in the presence of Ru-loaded zeolites and trace amounts of mineral acid [J].

Geboers, Jan ;

Van de Vyver, Stijn ;

Carpentier, Kevin ;

Jacobs, Pierre ;

Sels, Bert .

CHEMICAL COMMUNICATIONS, 2011, 47 (19) :5590-5592

[6] Efficient catalytic conversion of concentrated cellulose feeds to hexitols with heteropoly acids and Ru on carbon [J].

Geboers, Jan ;

Van de Vyver, Stijn ;

Carpentier, Kevin ;

de Blochouse, Kevin ;

Jacobs, Pierre ;

Sels, Bert .

CHEMICAL COMMUNICATIONS, 2010, 46 (20) :3577-3579

[7] Direct Catalytic Conversion of Cellulose into Ethylene Glycol Using Nickel-Promoted Tungsten Carbide Catalysts [J].

Ji, Na ;

Zhang, Tao ;

Zheng, Mingyuan ;

Wang, Aiqin ;

Wang, Hui ;

Wang, Xiaodong ;

Chen, Jingguang G. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (44) :8510-8513

[8] Nickel-Promoted Tungsten Carbide Catalysts for Cellulose Conversion: Effect of Preparation Methods [J].

Ji, Na ;

Zheng, Mingyuan ;

Wang, Aiqin ;

Zhang, Tao ;

Chen, Jingguang G. .

CHEMSUSCHEM, 2012, 5 (05) :939-944

[9] Catalytic conversion of cellulose into ethylene glycol over supported carbide catalysts [J].

Ji, Na ;

Zhang, Tao ;

Zheng, Mingyuan ;

Wang, Aiqin ;

Wang, Hui ;

Wang, Xiaodong ;

Shu, Yuying ;

Stottlemyer, Alan L. ;

Chen, Jingguang G. .

CATALYSIS TODAY, 2009, 147 (02) :77-85

[10] Polyoxometalate-supported ruthenium nanoparticles as bifunctional heterogeneous catalysts for the conversions of cellobiose and cellulose into sorbitol under mild conditions [J].

Liu, Mi ;

Deng, Weiping ;

Zhang, Qinghong ;

Wang, Yanliang ;

Wang, Ye .

CHEMICAL COMMUNICATIONS, 2011, 47 (34) :9717-9719

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