Rhodium-catalyzed thiophosphinoylation reaction of 1,2-dienes with diphosphine disulfides

被引：12

作者：

Arisawa, Mieko ^{[1
]}

Yamaguchi, Masahiko ^{[1
]}

机构：

[1] Tohoku Univ, WPI Adv Inst Mat Res, Dept Organ Chem, Grad Sch Pharmaceut Sci, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 01期

关键词：

ORGANOSULFUR COMPOUNDS; RADICAL-ADDITION; ALKYNES; ALLENES; TETRAPHENYLDIPHOSPHINE; HYDROPHOSPHINATION; PHOSPHINE; SALTS;

D O I：

10.1016/j.tetlet.2008.10.075

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of RhH(PPh3)(4), the reaction of 1,2-alkadienes, tetramethyldiphosphine disulfide, and camphorsulfonic acid gave (E)-2-dimethylthiophosphinoyl-2-alkenes. The reaction involved the P-P cleavage and the transfer of the thiophosphinoyl group to 1,2-alkadienes with concomitant formation of thiophosphinic anhydride. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：45 / 47

页数：3

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