Nitrosonium cation in chemical and biochemical reactions: achievements and prospects

被引：12

作者：

Borodkin, Gennady I. ^{[1
]}

Shubin, Vyacheslav G. ^{[2
]}

机构：

[1] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Dept Phys Organ Chem,NIOCH SB RAS, Prosp Akademika Lavrentieva 9, Novosibirsk 630090, Russia

[2] Russian Acad Sci, Siberian Branch, NN Vorozhtsov Novosibirsk Inst Organ Chem, Dept Phys Organ Chem, Prosp Akademika Lavrentieva 9, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2017年 / 86卷 / 01期

关键词：

WALLED CARBON NANOTUBES; ELECTROPHILIC AROMATIC NITRATION; RAY STRUCTURAL-CHARACTERIZATION; SELECTIVE CATALYTIC-REDUCTION; NO-DEPENDENT MODIFICATIONS; GAS-PHASE NITROSATION; NITRIC-OXIDE; CHARGE-TRANSFER; S-NITROSATION; RADICAL CATIONS;

D O I：

10.1070/RCR4662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Data on the reactivity of nitrosonium cation in chemical reactions are systematized and integrated. The review demonstrates the structural diversity of nitrosonium complexes resulting from the specific features of the electronic structure of NO+. The use of nitrosonium salts in the synthesis of heterocyclic compounds and for the preparation of modern materials, including nanomaterials, is considered. The participation of NO+ in oxidative, catalytic and biochemical processes is discussed. The bibliography includes 332 references.

引用

页码：18 / 46

页数：29

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