Nanostructured Pyrophosphate Na2PdP2O7-Catalyzed Suzuki-Miyaura Cross-Coupling Under Microwave Irradiation

被引：13

作者：

Danoun, Karim ^{[1
,2
]}

Essamlali, Younes ^{[1
]}

Amadine, Othmane ^{[1
]}

Tabit, Rida ^{[2
]}

Fihri, Aziz ^{[1
]}

Len, Christophe ^{[3
,4
]}

Zahouily, Mohamed ^{[1
,2
]}

机构：

[1] MASCIR Fdn, Rabat Design, Rue Mohamed El Jazouli, Rabat 10100, Morocco

[2] Univ Hassan II Casablanca, FST, URAC 24, Lab Mat Catalyse & Valorisat Ressources Nat, BP 146, Casablanca 20650, Morocco

[3] Ctr Rech Royallieu, Transformat Integrees Mat Renouvelable, UTC ESCOM, BP 20529, F-60205 Compiegne, France

[4] PSL Res Univ, CNRS, Inst Rech Chim Paris, Chim ParisTech, 11 Rue Pierre & Marie Curie, F-75231 Paris 05, France

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2018年 / 32卷 / 04期

关键词：

green chemistry; heterogeneous catalysis; microwave irradiation; palladium pyrophosphate; Suzuki-Miyaura reaction; HETEROGENEOUS PALLADIUM CATALYSTS; HIGHLY EFFICIENT CATALYST; PURE WATER; OXIDATIVE DEHYDROGENATION; ORGANOBORON COMPOUNDS; PHOSPHATE CATALYSTS; ARYLBORONIC ACIDS; ARYL CHLORIDES; ISO-BUTANE; 5-IODO-2'-DEOXYURIDINE;

D O I：

10.1002/aoc.4232

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Nanostructured palladium pyrophosphate (Na2PdP2O7) catalyst was synthesized and well characterized by using different techniques (TGA, XRD, SEM, TEM....). This nanocatalyst exhibited excellent catalytic activity in the synthesis of biaryl compounds via Suzuki-Miyaura cross-coupling to produce their corresponding products in good to excellent yields under mild conditions. The catalyst is recyclable and was recycled for four runs for the reaction of 4-bromoacetophenone with phenylboronic acid without appreciable loss of its catalytic activity.

引用

页数：10

共 54 条

[51] Carbon-carbon coupling reactions catalyzed by heterogeneous palladium catalysts [J].

Yin, Lunxiang ;

Liebscher, Juergen .

CHEMICAL REVIEWS, 2007, 107 (01) :133-173

[52]

Zapf A, 2000, ANGEW CHEM INT EDIT, V39, P4153, DOI 10.1002/1521-3773(20001117)39:22<4153::AID-ANIE4153>3.0.CO

[53]

2-T

[54] Crystal and band structures, bonding, and optical properties of solid compounds of alkaline indium (III) pyrophosphates MInP2O7 (M = Na, K, Rb, Cs) [J].

Zhang, YC ;

Cheng, WD ;

Wu, DS ;

Zhang, H ;

Chen, DG ;

Gong, YJ ;

Kan, ZG .

CHEMISTRY OF MATERIALS, 2004, 16 (21) :4150-4159

← 1 2 3 4 5 6 →