Synthesis, crystal structure, magnetic properties and EPR studies of Cu/Hg bimetallic thiocyanato-bridged coordination polymer

被引：19

作者：

Kruszynski, Rafal ^{[1
]}

Machura, Barbara ^{[2
]}

Wolff, Mariusz ^{[2
]}

Kusz, Joachim ^{[3
]}

Mrozinski, Jerzy ^{[4
]}

Bienko, Alina ^{[4
]}

机构：

[1] Tech Univ Lodz, Inst Gen & Ecol Chem, Dept Xray Crystallog & Crystal Chem, PL-90924 Lodz, Poland

[2] Silesian Univ, Inst Chem, Dept Inorgan & Radiat Chem, PL-40006 Katowice, Poland

[3] Silesian Univ, Inst Phys, PL-40006 Katowice, Poland

[4] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 04期

关键词：

Coordination polymer; Heterometallic complexes; Magnetic properties; Copper and mercury; MOLECULAR-STRUCTURE; COMPLEXES; CHEMISTRY; CADMIUM; LIGANDS; SOLIDS;

D O I：

10.1016/j.ica.2008.05.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new Cu/Hg bimetallic thiocyanato-bridged coordination polymer, [Cu(2-bzpy)Hg(SCN)(4)](n), has been synthesized and characterized by elemental analysis, magnetic measurements, EPR, and X-ray crystallography. X-ray diffraction analysis reveals that the title complex structure creates 3D network. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1369 / 1373

页数：5

共 36 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

[Anonymous], 2014, SPECTROCHIM ACTA A, DOI DOI 10.1016/j.saa.2013.11.069

[3]

[Anonymous], 1997, SHELXL97 PROGRAM SOL

[4]

Biradha K, 2000, ANGEW CHEM INT EDIT, V39, P3843, DOI 10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO

[5]

2-#

[6] SIMULTANEOUS BINDING OF BETAINE AND PSEUDOHALIDE TO CADMIUM - STRUCTURES OF 4 POLYMERIC MIXED-LIGAND CADMIUM(II) COMPLEXES [J].

CHOW, MY ;

CHEN, XM ;

MAK, TCW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (22) :3413-3420

[7] SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF A NEW CLASS OF HETEROTETRANUCLEAR COMPOUNDS WITH THIOCYANATE GROUPS AS BRIDGING LIGANDS - THE X-RAY STRUCTURE OF BIS-(MU-TETRAKIS(THIOCYANATO-S)MERCURY(II)-N,N')DIAQUAHEXAKIS-(5.7-DIMETHYL[1,2,4]TRIAZOLO[1,5-ALPHA]PYRIMIDINE-N3) DICOBALT(II) [J].

CINGI, MB ;

LANFREDI, AMM ;

TIRIPICCHIO, A ;

HAASNOOT, JG ;

REEDIJK, J .

INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1984, 86 (02) :137-143

[8] MAGNETIC EXCHANGE IN TRANSITION-METAL COMPLEXES .8. MOLECULAR FIELD-THEORY OF INTERCLUSTER INTERACTIONS IN TRANSITION-METAL CLUSTER COMPLEXES [J].

GINSBERG, AP ;

LINES, ME .

INORGANIC CHEMISTRY, 1972, 11 (09) :2289-&

[9] BIOMIMETIC CHEMISTRY OF NICKEL [J].

HALCROW, MA ;

CHRISTOU, G .

CHEMICAL REVIEWS, 1994, 94 (08) :2421-2481

[10] Heterobimetallic thiocyanato-bridged coordination polymers based on [Hg(SCN)4]2-:: Synthesis, crystal structure, magnetic properties and ESR studies [J].

Jian, Fang-Fang ;

Xiao, Hai-Lian ;

Liu, Fa Qian .

JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (12) :3695-3703

← 1 2 3 4 →