A divergent synthesis of 3,10-dialkylpicenes

被引：15

作者：

Chen, Xi-Chao ^{[1
]}

Nishinaga, Shuhei ^{[1
]}

Okuda, Yasuhiro ^{[1
]}

Zhao, Jia-Ji ^{[1
]}

Xu, Jie ^{[1
]}

Mori, Hiroki ^{[1
]}

Nishihara, Yasushi ^{[1
,2
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Earth Life & Mol Sci, Kita Ku, Okayama 7008530, Japan

[2] Japan Sci & Technol Agcy, ACT C, Kawaguchi, Saitama 3320012, Japan

来源：

Organic Chemistry Frontiers | 2015年 / 2卷 / 05期

关键词：

FIELD-EFFECT TRANSISTORS; CROSS-COUPLING REACTIONS; CARBON-OXYGEN BONDS; ORGANIC SEMICONDUCTORS; SUBSTITUTED PICENES; GRIGNARD-REAGENTS; HIGH-PERFORMANCE; METHYL ETHERS; THIN-FILMS; ARYL;

D O I：

10.1039/c5qo00039d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of 3,10-dialkylated picenes has been synthesized from 3,10-dimethoxypicene through a divergent approach involving Ni-catalyzed alkynylation of a C-O bond, alkylation, and hydrogenation.

引用

页码：536 / 541

页数：6