Metal-Organic Polyhedron Based on a CuII Paddle-Wheel Secondary Building Unit at the Truncated Octahedron Corners

被引：60

作者：

Prakash, M. Jaya ^{[1
]}

Zou, Yang ^{[1
]}

Hong, Seunghee ^{[1
]}

Park, Mira ^{[1
]}

Bui, Minh-Phuong Ngoc ^{[1
]}

Seong, Gi Hun ^{[1
]}

Lah, Myoung Soo ^{[1
]}

机构：

[1] Hanyang Univ, Dept Chem & Appl Chem, Ansan 426791, Kyunggi Do, South Korea

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 04期

关键词：

2-DIMENSIONAL NETWORK; COORDINATION POLYMER; BLOCKS SBBS; FRAMEWORKS; DESIGN; LIGANDS; COMPLEXES; CAVITIES; CAPSULE; SITES;

D O I：

10.1021/ic802382p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Site-directed mutagenesis of Pseudomonas aeruginosa azurin C112D at the M121 position has afforded a series of proteins with elevated Cu-II/I reduction potentials relative to the Cull aquo ion. The high potential and low axial hyperfine splitting (Cu-II electron paramagnetic resonance A(parallel to)) of the C112D/M121L protein are remarkably similar to features normally associated with type 1 copper centers.

引用

页码：1281 / +

页数：4

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