Luminescence shift of electrospun ZnO/MEH-PPV/PEO composite nanofibers

被引:5
作者
Cho, Mi Yeon [1 ]
Cho, Kyoungah [1 ]
Kim, Sangsig [1 ]
机构
[1] Korea Univ, Dept Elect Engn, Seoul 136701, South Korea
关键词
ZnO nanoparticle; MEH-PPV; Electrospun fibers; Luminescence; ZNO QUANTUM DOTS; HYBRID SOLAR-CELLS; CONJUGATED POLYMER; OPTICAL PHONONS; NANOPARTICLES; FIBERS; ORIGIN; FILMS;
D O I
10.1016/j.jlumin.2012.09.009
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The photoluminescence characteristics of electrospun ZnO/poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene]/poly(ethylene oxide) (ZnO/MEH-PPV/PEO) composite nanofibers with various composite ratios of ZnO nanoparticles (NPs) and MEH-PPV are investigated in this study. The photoluminescence spectra of the nanofibers show sequential red- and blue-shifts in the peak wavelength with increasing concentration of ZnO NPs. For the nanofibers in which their concentration is relatively low, the dispersed ZnO NPs induce the aggregation of MEH-PPV, resulting in the red-shift of the peaks. In contrast, for the nanofibers with relatively high concentrations of ZnO NPs (over 50%), the blue-shift of the peaks occurs. The mechanisms of the red- and blue-shifts are discussed in this paper. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 82
页数:4
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