Rechargeable antimicrobial coatings for poly(lactic acid) nonwoven fabrics

被引:40
作者
Cerkez, Idris [1 ]
Worley, S. D. [1 ]
Broughton, R. M. [2 ]
Huang, T. S. [3 ]
机构
[1] Auburn Univ, Dept Chem & Biochem, Auburn, AL 36849 USA
[2] Auburn Univ, Dept Polymer & Fiber Engn, Auburn, AL 36849 USA
[3] Auburn Univ, Dept Poultry Sci, Auburn, AL 36849 USA
关键词
Antimicrobial; N-halamine; Poly(lactic acid); HALAMINE POLYMERIC BIOCIDES; N-HALAMINE; GRAFT-POLYMERIZATION; ALLYL MONOMER; ANTIBACTERIAL; POLY(ETHYLENE-TEREPHTHALATE); POLYPROPYLENE; COPOLYMERS; CHITOSAN; LIGHT;
D O I
10.1016/j.polymer.2012.11.049
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A novel heterocyclic N-halamine acetate homopolymer was synthesized and characterized by ATR-IR, NMR and MALDI-TOF spectroscopy and TGA and DSC analysis. The homopolymer was coated onto poly(lactic acid) (PLA) meltblown nonwoven fabric, and the surfaces were rendered biocidal upon exposure to dilute sodium hypochlorite solution. The coatings were quite stable versus UVA and florescent light exposure. Moreover, they exhibited long-term shelf-life stability, and they were rechargeable when oxidative chlorine on the surfaces was partially exhausted after three months storage. It was found that the chlorinated fabrics exhibited effective antimicrobial activity with about six logs inactivation of Staphylococcus aureus and Escherichia coli O157:H7 within 30 min of contact time. The coated PLA possesses potential for use in antimicrobial food packaging, filters, and hygiene products. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:536 / 541
页数:6
相关论文
共 40 条
[1]   Graft Polymerization of N-tert-Butylacrylamide Onto Polypropylene During Melt Extrusion and Biocidal Properties of its Products [J].
Badrossamay, Mohammad Reza ;
Sun, Gang .
POLYMER ENGINEERING AND SCIENCE, 2009, 49 (02) :359-368
[2]   Development of antimicrobial stainless steel via surface modification with N-halamines: Characterization of surface chemistry and N-halamine chlorination [J].
Bastarrachea, Luis J. ;
Goddard, Julie M. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 127 (01) :821-831
[3]   Infection control - A problem for patient safety [J].
Burke, JP .
NEW ENGLAND JOURNAL OF MEDICINE, 2003, 348 (07) :651-656
[4]   Novel silver-based nanoclay as an antimicrobial in polylactic acid food packaging coatings [J].
Busolo, Maria A. ;
Fernandez, Patricia ;
Ocio, Maria J. ;
Lagaron, Jose M. .
FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT, 2010, 27 (11) :1617-1626
[5]   N-Halamine-based chitosan: Preparation, characterization, and antimicrobial function [J].
Cao, Zhengbing ;
Sun, Yuyu .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART A, 2008, 85A (01) :99-107
[6]   Rechargeable Antibacterial and Antifungal Polymeric Silver Sulfadiazines [J].
Cao, Zhengbing ;
Sun, Xinbo ;
Sun, Yuyu ;
Fong, Hao .
JOURNAL OF BIOACTIVE AND COMPATIBLE POLYMERS, 2009, 24 (04) :350-367
[7]   N-halamine copolymers for biocidal coatings [J].
Cerkez, Idris ;
Kocer, Hasan B. ;
Worley, S. D. ;
Broughton, R. M. ;
Huang, T. S. .
REACTIVE & FUNCTIONAL POLYMERS, 2012, 72 (10) :673-679
[8]   Epoxide tethering of polymeric N-halamine moieties [J].
Cerkez, Idris ;
Kocer, Hasan B. ;
Worley, S. D. ;
Broughton, R. M. ;
Huang, T. S. .
CELLULOSE, 2012, 19 (03) :959-966
[9]   Multifunctional cotton fabric: Antimicrobial and durable press [J].
Cerkez, Idris ;
Kocer, Hasan B. ;
Worley, S. D. ;
Broughton, R. M. ;
Huang, T. S. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 124 (05) :4230-4238
[10]   N-Halamine Biocidal Coatings via a Layer-by-Layer Assembly Technique [J].
Cerkez, Idris ;
Kocer, Hasan B. ;
Worley, S. D. ;
Broughton, R. M. ;
Huang, T. S. .
LANGMUIR, 2011, 27 (07) :4091-4097