Cage Shrinkage of Fullerene via a C2 Loss: from IPR C90(28)Cl24 to Nonclassical, Heptagon-Containing C88Cl22/24

被引：33

作者：

Ioffe, Ilya N. ^{[1
]}

Mazaleva, Olga N. ^{[1
]}

Sidorov, Lev N. ^{[1
]}

Yang, Shangfeng ^{[2
]}

Wei, Tao ^{[2
]}

Kemnitz, Erhard ^{[3
]}

Troyanov, Sergey I. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

[2] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

[3] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 24期

基金：

俄罗斯基础研究基金会; 中国国家自然科学基金;

关键词：

CHLORINATION; TRANSFORMATION; DERIVATIVES;

D O I：

10.1021/ic402556g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new case of chlorination-promoted fullerene cage shrinkage is reported. Chlorination of C-90 (isolated pentagon rule isomer no. 28) with VCl4 afforded C88Cl22 with a nonclassic carbon cage (NCC) containing 1 heptagon and 13 pentagons including 2 fused pairs flanking the heptagon. The pathway of C-2 abstraction from the C-90 cage is suggested on the basis of density functional theory calculations.

引用

页码：13821 / 13823

页数：3

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