Microwave-assisted synthesis, spectroscopy and biological aspects of binuclear titanocene chelates of isatin-2,3-bis(thiosemicarbazones)

被引：7

作者：

Banerjee, Priyanka ^{[1
]}

Pandey, Om P. ^{[1
]}

Sengupta, Soumitra K. ^{[1
]}

机构：

[1] DDU Gorokhpur Univ, Dept Chem, Orgonomet Res Lab, Gorakhpur 273009, Uttar Pradesh, India

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2009年 / 23卷 / 01期

关键词：

titanium(IV); bis(thiosemicarbazones); IR; NMR; fungicidal; viricidal and bactericidal; TRANSITION-METAL-COMPLEXES; CRYSTAL; THIOSEMICARBAZONES; SEMICARBAZONES; COPPER(II);

D O I：

10.1002/aoc.1464

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The reactions of bis(cyclopentadienyl)titanium(IV) chloride with a new class of bis(thiosemicarbazones) (H2L), derived by condensing isatin with different N(4)-substituted thiosemicarbazides, have been studied both by a conventional stirring method and also using microwave technology. Binuclear products of type [{(eta(5)-C5H5)(2)TiCl}(2)(L)] have been isolated in both cases. Tentative structural conclusions are drawn for the reaction products based upon analysis, electrical conductance, magnetic moment and spectral (UV-visible, IR, H-1 NMR and C-13 NMR) data. FAB mass spectra of these compounds were also recorded to confirm the binuclear structures. Studies were conducted to assess the growth inhibiting potential of the ligands and complexes against various fungal, viral and bacterial strains. Copyright (C) 2008 John Wiley & Sons, Ltd.

引用

页码：19 / 23

页数：5

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