Investigation of MoS2 and Graphene Nanosheets by Magnetic Force Microscopy

被引:120
作者
Li, Hai [1 ]
Qi, Xiaoying [2 ]
Wu, Jumiati [1 ]
Zeng, Zhiyuan [1 ]
Wei, Jun [2 ]
Zhang, Hua [1 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Singapore Inst Mfg Technol, Singapore 638075, Singapore
基金
新加坡国家研究基金会;
关键词
magnetic force microscopy; MoS2; graphene; nanosheet; phase shift; SINGLE-LAYER MOS2; OPTICAL-IDENTIFICATION; NANOPARTICLES; OXIDE; MICA;
D O I
10.1021/nn400443u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the first time, magnetic force microscopy (MFM) is used to characterize the mechanically exfoliated single- and few-layer MoS2 and graphene nanosheets. By analysis of the phase and amplitude shifts, the magnetic response of MoS2 and graphene nanosheets exhibits the dependence on their layer number. However, the solution-processed single-layer MoS2 nanosheet shows the reverse magnetic signal to the mechanically exfoliated one, and the graphene oxide nanosheet has not shown any detectable magnetic signal. Importantly, graphene and MoS2 flakes become nonmagnetic when they exceed a certain thickness.
引用
收藏
页码:2842 / 2849
页数:8
相关论文
共 58 条
[1]   Visibility of dichalcogenide nanolayers [J].
Benameur, M. M. ;
Radisavljevic, B. ;
Heron, J. S. ;
Sahoo, S. ;
Berger, H. ;
Kis, A. .
NANOTECHNOLOGY, 2011, 22 (12)
[2]   Metallic and ferromagnetic edges in molybdenum disulfide nanoribbons [J].
Botello-Mendez, A. R. ;
Lopez-Urias, F. ;
Terrones, M. ;
Terrones, H. .
NANOTECHNOLOGY, 2009, 20 (32)
[3]   Optical identification of atomically thin dichalcogenide crystals [J].
Castellanos-Gomez, A. ;
Agrait, N. ;
Rubio-Bollinger, G. .
APPLIED PHYSICS LETTERS, 2010, 96 (21)
[4]   Highly Efficient Electrocatalytic Hydrogen Production by MoSx Grown on Graphene-Protected 3D Ni Foams [J].
Chang, Yung-Huang ;
Lin, Cheng-Te ;
Chen, Tzu-Yin ;
Hsu, Chang-Lung ;
Lee, Yi-Hsien ;
Zhang, Wenjing ;
Wei, Kung-Hwa ;
Li, Lain-Jong .
ADVANCED MATERIALS, 2013, 25 (05) :756-760
[5]  
Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/nchem.1589, 10.1038/NCHEM.1589]
[6]   Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].
Coleman, Jonathan N. ;
Lotya, Mustafa ;
O'Neill, Arlene ;
Bergin, Shane D. ;
King, Paul J. ;
Khan, Umar ;
Young, Karen ;
Gaucher, Alexandre ;
De, Sukanta ;
Smith, Ronan J. ;
Shvets, Igor V. ;
Arora, Sunil K. ;
Stanton, George ;
Kim, Hye-Young ;
Lee, Kangho ;
Kim, Gyu Tae ;
Duesberg, Georg S. ;
Hallam, Toby ;
Boland, John J. ;
Wang, Jing Jing ;
Donegan, John F. ;
Grunlan, Jaime C. ;
Moriarty, Gregory ;
Shmeliov, Aleksey ;
Nicholls, Rebecca J. ;
Perkins, James M. ;
Grieveson, Eleanor M. ;
Theuwissen, Koenraad ;
McComb, David W. ;
Nellist, Peter D. ;
Nicolosi, Valeria .
SCIENCE, 2011, 331 (6017) :568-571
[7]   Photoluminescence from Chemically Exfoliated MoS2 [J].
Eda, Goki ;
Yamaguchi, Hisato ;
Voiry, Damien ;
Fujita, Takeshi ;
Chen, Mingwei ;
Chhowalla, Manish .
NANO LETTERS, 2011, 11 (12) :5111-5116
[8]   Induced magnetic ordering by proton irradiation in graphite -: art. no. 227201 [J].
Esquinazi, P ;
Spemann, D ;
Höhne, R ;
Setzer, A ;
Han, KH ;
Butz, T .
PHYSICAL REVIEW LETTERS, 2003, 91 (22)
[9]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[10]   Magnetic force microscopy [J].
Hartmann, U .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1999, 29 :53-87