Self-Assembly of Large Scale CdS/TiO2 Film Photocatalyst

被引：3
|
作者：
Li, Chunxiang [1 ]
Jiang, Zhaohua [1 ]
Yao, Zhongping [1 ]
机构：
[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China
来源：
RENEWABLE AND SUSTAINABLE ENERGY II, PTS 1-4 | 2012年 / 512-515卷
关键词：
CdS/TiO2; Photoreduction; Raman; Luminescence; Crystal size; HYDROGEN-PRODUCTION; CHARGE-TRANSFER; CDS; NANOPARTICLES; NANOCRYSTALS; CDS-TIO2; WATER;
D O I：
10.4028/www.scientific.net/AMR.512-515.1692
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
CdS/TiO2 composite films with different Cd:Ti atomic ratio were prepared by a new straightforward particulate layer-by-layer method. Titanium dihydroxide and thiourea were used as precursors. Raman and X-ray photoelectron spectroscopy analysis for the composite films revealed that the TiO2 formed from titanium precursor retarded the crystal growth of CdS. Luminescence and UV-vis absorption spectra investigation showed that emission and absorption band of CdS/TiO2 blue shifted as crystal size of CdS decreased. Furthermore, hydrogen formation curves revealed that hydroxyl of CdS/TiO2 films plays an important role in water splitting reaction under both UV and visible light irradiations.
引用
收藏
页码：1692 / 1698
页数：7
相关论文
共 50 条
  • [1] Self-assembly, photophysical and electrochemical properties and activation of the TiO2 photocatalyst by perylene bisimide
    Senthilraja, Adhimoolam
    Krishnakumar, Balu
    Swaminathan, Meenakshisundaram
    Nagarajan, Samuthira
    NEW JOURNAL OF CHEMISTRY, 2014, 38 (04) : 1573 - 1580
  • [2] Large-scale superlattices from colloidal TiO2 nanorods: A facile self-assembly approach
    Zhang, Yong
    Liu, Fa-Min
    APPLIED SURFACE SCIENCE, 2016, 367 : 559 - 562
  • [3] Template-free self-assembly of a nanoporous TiO2 thin film
    Gao, Yanfeng
    Nagai, Masayuki
    Seo, Won-Seon
    Koumoto, Kunihito
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (03) : 831 - 837
  • [4] Assembly and photoelectrochemical studies of TiO2/CdS nanocomposite film
    Hao, EC
    Qian, XM
    Yang, B
    Wang, DJ
    Shen, JC
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1999, 337 : 181 - 184
  • [5] Self-Assembly of Large-Scale Floating TiO2 Nanorod Arrays at the Gas-Liquid Interface
    Xia, Hua-Rong
    Li, Jia
    Peng, Chen
    Li, Long-Wei
    Sun, Wen-Tao
    Peng, Lian-Mao
    ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (18) : 8850 - 8852
  • [6] Fabrication of TiO2 thin film by electrostatic self-assembly method on optical fiber
    Han, J
    Du, HY
    Wang, YL
    JOURNAL OF RARE EARTHS, 2005, 23 : 243 - 246
  • [7] Fabrication of TiO2 Thin Film by Electrostatic Self-Assembly Method on Optical Fiber
    韩晶
    杜海燕
    王玉玲
    JournalofRareEarths, 2005, (S1) : 243 - 246
  • [8] Self-assembly of photoactive TiO2 - cyclodextrin wires
    1600, American Chemical Society, Columbus, United States (127):
  • [9] Cyclodextrin directed self-assembly of TiO2 nanoparticles
    Yoon, Sungkwon
    Nichols, William T.
    APPLIED SURFACE SCIENCE, 2013, 285 : 517 - 523
  • [10] Self-assembly and characterization of nanostructural TiO2/PS and TiO2 hollow spheres
    Song, XQ
    Yang, XH
    Chen, RF
    Wei, Y
    ACTA CHIMICA SINICA, 2006, 64 (03) : 198 - 202
12345