Direct synthesis of zeolitic imidazolate framework-8/chitosan composites in chitosan hydrogels

被引：120

作者：

Yao, Jianfeng ^{[1
]}

Chen, Rizhi ^{[1
]}

Wang, Kun ^{[1
]}

Wang, Huanting ^{[1
]}

机构：

[1] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2013年 / 165卷

基金：

澳大利亚研究理事会;

关键词：

Zeolitic imidazolate framework-8; Chitosan; Polymer hydrogel; Crystallization; CAPTURE PROPERTIES; FRAMEWORKS; SIZE; PERFORMANCE; MEMBRANES; NANOCRYSTALS; SEPARATIONS; ZIF-8;

D O I：

10.1016/j.micromeso.2012.08.018

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Zeolitic imidazolate framework-8 (ZIF-8)/chitosan composites were prepared in the chitosan hydrogels. The concentrations of the chitosan and the alkaline solution were varied to the synthesis of the ZIF-8/chitosan composites. In the chitosan hydrogels with the addition of ammonium hydroxide solution, the resulting ZIF-8 crystals exhibited an unusual XRD structure that the XRD peak at about 18 degrees (222) became the strongest. The XRD peak intensity ratio of (222)/(011) increased from 0.68 to 1.5-5.2 in the presence of chitosan hydrogels. ZIF-8/chitosan composites (FC2) were composed of aggregated nano-sized particles, and exhibited a higher CO2 adsorption than normal ZIF-8 crystals. After removing chitosan from FC2, XRD pattern of the resulting ZIF-8 crystals returned to the normal state and the morphology kept the same as the composite. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：200 / 204

页数：5

共 29 条

[1] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[2] Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis [J].

Bux, Helge ;

Liang, Fangyi ;

Li, Yanshuo ;

Cravillon, Janosch ;

Wiebcke, Michael ;

Caro, Juergen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) :16000-+

[3] Fast Nucleation and Growth of ZIF-8 Nanocrystals Monitored by Time-Resolved In Situ Small-Angle and Wide-Angle X-Ray Scattering [J].

Cravillon, Janosch ;

Schroeder, Christian A. ;

Nayuk, Roman ;

Gummel, Jeremie ;

Huber, Klaus ;

Wiebcke, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (35) :8067-8071

[4] Rapid Room-Temperature Synthesis and Characterization of Nanocrystals of a Prototypical Zeolitic Imidazolate Framework [J].

Cravillon, Janosch ;

Muenzer, Simon ;

Lohmeier, Sven-Jare ;

Feldhoff, Armin ;

Huber, Klaus ;

Wiebcke, Michael .

CHEMISTRY OF MATERIALS, 2009, 21 (08) :1410-1412

[5] Effect of zeolitic imidazolate frameworks on the gas transport performance of ZIF8-poly(1,4-phenylene ether-ether-sulfone) hybrid membranes [J].

Diaz, Kenya ;

Lopez-Gonzalez, Mar ;

del Castillo, Luis F. ;

Riande, Evaristo .

JOURNAL OF MEMBRANE SCIENCE, 2011, 383 (1-2) :206-213

[6] GaN@ZIF-8: Selective Formation of Gallium Nitride Quantum Dots inside a Zinc Methylimidazolate Framework [J].

Esken, Daniel ;

Turner, Stuart ;

Wiktor, Christian ;

Kalidindi, Suresh Babu ;

Van Tendeloo, Gustaaf ;

Fischer, Roland A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (41) :16370-16373

[7] ZnO@ZIF-8: stabilization of quantum confined ZnO nanoparticles by a zinc methylimidazolate framework and their surface structural characterization probed by CO2 adsorption [J].

Esken, Daniel ;

Noei, Heshmat ;

Wang, Yuemin ;

Wiktor, Christian ;

Turner, Stuart ;

Van Tendeloo, Gustaaf ;

Fischer, Roland A. .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (16) :5907-5915

[8] A high-performance chitosan-based double layer proton exchange membrane with reduced methanol crossover [J].

Hasani-Sadrabadi, Mohammad Mahdi ;

Dashtimoghadam, Erfan ;

Majedi, Fatemeh S. ;

Emami, Shahriar Hojjati ;

Moaddel, Homayoun .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (10) :6105-6111

[9] Zeolite a imidazolate frameworks [J].

Hayashi, Hideki ;

Cote, Adrien P. ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

NATURE MATERIALS, 2007, 6 (07) :501-506

[10] In situ high pressure study of ZIF-8 by FTIR spectroscopy [J].

Hu, Yue ;

Kazemian, Hossein ;

Rohani, Sohrab ;

Huang, Yining ;

Song, Yang .

CHEMICAL COMMUNICATIONS, 2011, 47 (47) :12694-12696

← 1 2 3 →