Rare-earth metal catalysts for alkene hydrosilylation

被引:51
作者
Liu, Deshuai [1 ,2 ]
Liu, Boyu [1 ,2 ]
Pan, Zexiong [1 ,2 ]
Li, Jianfeng [1 ,2 ]
Cui, Chunming [1 ,2 ,3 ]
机构
[1] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
[3] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
rare-earth metal; hydrosilylation; alkene; catalysis; mechanism; REGIOSELECTIVE HYDROSILYLATION; HYDRIDE COMPLEXES; ALKYL COMPLEXES; POLYMERIZATION; EFFICIENT; LIGANDS; HYDROAMINATION/CYCLIZATION; HYDROSILATION; MECHANISM; ETHYLENE;
D O I
10.1007/s11426-018-9403-7
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rare-earth metal catalyzed hydrosilylation of alkenes has emerged as a powerful and selective strategy for the synthesis of organosilanes. This transformation can offer distinctive catalytic sequences and reaction patterns from other catalysts because of the high electropositivity and lack of oxidative-addition process of rare-earth metal. This review summarizes the rare-earth metal catalysts for hydrosilylation of alkene according to the type of ligands. The synthesis and structure of rare-earth metal catalysts, the substrate scope as well as some preliminary structure-activity relationship and mechanism are discussed.
引用
收藏
页码:571 / 582
页数:12
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