A 'turn-on' fluorescent chemosensor based on rhodamine-N-(3-aminopropyl)-imidazole for detection of Al3+ ions

被引:54
作者
Li, Zhengqiang [1 ]
Hu, Qiuping [1 ]
Li, Chunxiao [1 ]
Dou, Jintao [1 ]
Cao, Jiaojie [1 ]
Chen, Weikai [1 ]
Zhu, Qingzeng [1 ]
机构
[1] Shandong Univ, Sch Chem & Chem Engn, Key Lab Special Funct Aggregated Mat, Minist Educ, Jinan 250199, Peoples R China
关键词
Fluorescent chemosensor; Rhodamine; Al3+; Spirolactam ring; RHODAMINE-BASED FLUORESCENT; SELECTIVE FLUORESCENT; AQUEOUS-SOLUTION; CHEMODOSIMETER; ALUMINUM; PROBE; SENSOR;
D O I
10.1016/j.tetlet.2014.01.026
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel N-(3-aminopropyl)-imidazole-appended rhodamine-based fluorescent chemosensor was synthesized. The sensing behavior and selectivity of the synthesized chemosensor toward metal cations were studied by UV/vis and fluorescence spectroscopy. The chemosensor recognized Al3+ ions by a significantly enhanced fluorescence and a visible color change due to opening of the spirolactam ring triggered by the addition of Al3+ ions. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1258 / 1262
页数:5
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