Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

被引：141
|
作者：
Zhuo, Chun-Xiang [1 ]
You, Shu-Li [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期
关键词：
allylic dearomatization; arenes; asymmetric catalysis; palladium; synthetic methods; ENANTIOSELECTIVE SYNTHESIS; BOND FORMATION; C-ALLYLATION; OXIDATIVE DEAROMATIZATION; QUATERNARY STEREOCENTER; PHENOL DEAROMATIZATION; BIFUNCTIONAL CATALYST; ALKYLATION REACTIONS; WORKING MODEL; CONSTRUCTION;
D O I：
10.1002/anie.201304591
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Baring all: The title reaction provides β-naphthalenones bearing an all-carbon quaternary center in good to excellent yields, as well as excellent chemo- and enantioselectivity (see scheme). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10056 / 10059
页数：4
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