Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

被引：139
|
作者：
Zhuo, Chun-Xiang [1 ]
You, Shu-Li [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期
关键词：
allylic dearomatization; arenes; asymmetric catalysis; palladium; synthetic methods; ENANTIOSELECTIVE SYNTHESIS; BOND FORMATION; C-ALLYLATION; OXIDATIVE DEAROMATIZATION; QUATERNARY STEREOCENTER; PHENOL DEAROMATIZATION; BIFUNCTIONAL CATALYST; ALKYLATION REACTIONS; WORKING MODEL; CONSTRUCTION;
D O I：
10.1002/anie.201304591
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Baring all: The title reaction provides β-naphthalenones bearing an all-carbon quaternary center in good to excellent yields, as well as excellent chemo- and enantioselectivity (see scheme). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10056 / 10059
页数：4
相关论文
共 50 条
  • [11] Palladium(0)-Catalyzed Intermolecular Allylic Dearomatization of Indoles by a Formal [4+2] Cycloaddition Reaction
    Gao, Run-Duo
    Xu, Qing-Long
    Zhang, Bo
    Gu, Yiting
    Dai, Li-Xin
    You, Shu-Li
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (33) : 11601 - 11604
  • [12] Palladium-Catalyzed Asymmetric Domino Heck/Carbocyclization/Suzuki Reaction: A Dearomatization of Nonactivated Naphthalenes
    Chen, Ming
    Wang, Xucai
    Ren, Zhi-Hui
    Guan, Zheng-Hui
    CCS CHEMISTRY, 2021, 3 (12): : 69 - 77
  • [13] Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of β-ketoesters: An Unusual Counterion Effect
    Trost, Barry M.
    Schaeffner, Benjamin
    Osipov, Maksim
    Wilton, Donna A. A.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (15) : 3548 - 3551
  • [14] Recent Developments in Palladium-Catalyzed Asymmetric Intermolecular Heck Reaction
    Li Hao
    Ding Changhua
    Xu Bin
    Hou Xuelong
    ACTA CHIMICA SINICA, 2014, 72 (07) : 765 - 770
  • [15] Ru-catalyzed intermolecular dearomatization reaction of indoles with allylic alcohols
    Zhang, Xiao
    Yang, Ze-Peng
    Liu, Chuan
    You, Shu-Li
    CHEMICAL SCIENCE, 2013, 4 (08) : 3239 - 3243
  • [16] Palladium-Catalyzed Asymmetric Intermolecular Cyclization
    Hu, Jian
    Hirao, Hajime
    Li, Yongxin
    Zhou, Jianrong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (33) : 8676 - 8680
  • [17] Iridium-Catalyzed Asymmetric Allylic Dearomatization by a Desymmetrization Strategy
    Wang, Ye
    Zheng, Chao
    You, Shu-Li
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (47) : 15093 - 15097
  • [18] Palladium-Catalyzed Asymmetric Reductive Heck Reaction of Aryl Halides
    Yue, Guizhou
    Lei, Kaining
    Hirao, Hajime
    Zhou, Jianrong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (22) : 6531 - 6535
  • [19] Palladium-catalyzed asymmetric allylic alkylation of ketone enolates
    Trost, BM
    Schroeder, GM
    CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (01) : 174 - 184
  • [20] Versatile ligands for palladium-catalyzed asymmetric allylic alkylation
    Dierkes, P
    Ramdeehul, S
    Barloy, L
    De Cian, A
    Fischer, J
    Kamer, PCJ
    van Leeuwen, PWNM
    Osborn, JA
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1998, 37 (22) : 3116 - 3118
12345