Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

被引：143

作者：

Zhuo, Chun-Xiang ^{[1
]}

You, Shu-Li ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期

关键词：

allylic dearomatization; arenes; asymmetric catalysis; palladium; synthetic methods; ENANTIOSELECTIVE SYNTHESIS; BOND FORMATION; C-ALLYLATION; OXIDATIVE DEAROMATIZATION; QUATERNARY STEREOCENTER; PHENOL DEAROMATIZATION; BIFUNCTIONAL CATALYST; ALKYLATION REACTIONS; WORKING MODEL; CONSTRUCTION;

D O I：

10.1002/anie.201304591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Baring all: The title reaction provides β-naphthalenones bearing an all-carbon quaternary center in good to excellent yields, as well as excellent chemo- and enantioselectivity (see scheme). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10056 / 10059

页数：4

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