Palladium-Catalyzed Intermolecular Asymmetric Allylic Dearomatization Reaction of Naphthol Derivatives

被引:143
作者
Zhuo, Chun-Xiang [1 ]
You, Shu-Li [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
关键词
allylic dearomatization; arenes; asymmetric catalysis; palladium; synthetic methods; ENANTIOSELECTIVE SYNTHESIS; BOND FORMATION; C-ALLYLATION; OXIDATIVE DEAROMATIZATION; QUATERNARY STEREOCENTER; PHENOL DEAROMATIZATION; BIFUNCTIONAL CATALYST; ALKYLATION REACTIONS; WORKING MODEL; CONSTRUCTION;
D O I
10.1002/anie.201304591
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Baring all: The title reaction provides β-naphthalenones bearing an all-carbon quaternary center in good to excellent yields, as well as excellent chemo- and enantioselectivity (see scheme). © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:10056 / 10059
页数:4
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