SnO-decorated TiO2 nanoparticle with enhanced photocatalytic performance for methylene blue degradation

被引:14
作者
Lee, Jae Kwon [1 ]
Kim, Yoon-Kee [1 ]
Choi, Byung Joon [2 ]
Chung, Taek-Mo [3 ,4 ]
Han, Jeong Hwan [2 ,4 ]
机构
[1] Hanbat Natl Univ, Dept Mat Sci & Engn, Deajeon 34014, South Korea
[2] Seoul Natl Univ Sci & Technol, Dept Mat Sci & Engn, Seoul 01811, South Korea
[3] Korea Res Inst Chem Technol, Div Adv Mat, 141 Gajeong Ro, Daejeon 34114, South Korea
[4] Univ Sci & Technol, Dept Chem Convergence Mat, 217 Gajeong Ro, Deajeon 34113, South Korea
关键词
Photocatalyst; Powder atomic layer deposition (P-ALD); SnO; TiO2; Methylene blue (MB) degradation; LAYER;
D O I
10.1016/j.apsusc.2019.02.175
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
P-type tin monoxide (SnO) decorated TiO2 nanoparticles have been synthesized by the powder atomic layer deposition (p-ALD) method in a fluidized bed reactor at 150-250 degrees C. Successful deposition of SnO on a TiO2 surface was realized using a precursor combination of Sn(dmamp)(2) and H2O as Sn source and reactant, respectively. Prepared SnO/TiO2 nanoparticles were characterized by XRF, XPS, XRD, and TEM-EDS. Formation of a p-SnO/n-TiO2 heterojunction resulted in improved photocatalytic methylene blue degradation performance compared to using a TiO2 photocatalyst, which might be attributed to facile separation of photo- induced electron-hole pairs as well as to increased UV/visible light absorption by adopting a narrow bandgap SnO.
引用
收藏
页码:1089 / 1092
页数:4
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