Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties

被引:147
作者
Chen, Xinglong [1 ]
Jing, Qun [2 ]
Ok, Kang Min [1 ]
机构
[1] Sogang Univ, Dept Chem, 35 Baekbeom Ro, Seoul 04107, South Korea
[2] Xinjiang Univ, Sch Phys Sci & Technol, 666 Shengli Rd, Urumqi 830046, Peoples R China
基金
中国国家自然科学基金; 新加坡国家研究基金会;
关键词
crystal growth; materials science; nonlinear optics; oxyhalides; second-harmonic generation; STRONG 2ND-HARMONIC GENERATION; LASER DAMAGE THRESHOLD; CRYSTAL-STRUCTURE; METAL-OXIDES; ZEOLITE-X; BAND-GAP; DESIGN; RB; PREDICTION; REGION;
D O I
10.1002/anie.202009541
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
To develop high-performance nonlinear optical (NLO) materials for infrared (IR) applications, we have applied a rational element-composition design strategy and investigated the unexplored PbO-PbCl2-PbI(2)system. By doing so, we discovered a new polar lead mixed oxyhalide, Pb18O8Cl15I5, the first synthetic metal oxyhalide combining both Cl(-)and I-. Pb(18)O(8)Cl(15)I(5)reveals an unprecedented structural feature with two different dimensional types of oxocentered Pb-O units, namely, [O4Pb8](8+)clusters and [OPb2](2+)chains. Centimeter-sized single crystals of Pb(18)O(8)Cl(15)I(5)have been successfully grown under ambient conditions. Remarkably, Pb(18)O(8)Cl(15)I(5)satisfies all fundamental yet rigorous criteria for high-performance IR NLO materials, exhibiting the widest IR transparency (up to 16.0 mu m) among oxide-based crystals, strong second-harmonic generation response (1.05xAgGaS(2)), superior birefringence (0.086 at 636 nm), and a high laser-induced damage threshold (8.5xAgGaS(2)).
引用
收藏
页码:20323 / 20327
页数:5
相关论文
共 85 条
[1]  
[Anonymous], 2019, ANGEW CHEM INT EDIT
[2]   Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study [J].
Bera, Tarun K. ;
Jang, Joon I. ;
Song, Jung-Hwan ;
Malliakas, Christos D. ;
Freeman, Arthur J. ;
Ketterson, John B. ;
Kanatzidis, Mercouri G. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (10) :3484-3495
[3]   LINEAR AND NONLINEAR OPTICAL PROPERTIES OF ZNGEP2 AND CDSE [J].
BOYD, GD ;
BUEHLER, E ;
STORZ, FG .
APPLIED PHYSICS LETTERS, 1971, 18 (07) :301-&
[4]   LINEAR AND NONLINEAR OPTICAL PROPERTIES OF SOME TERNARY SELENIDES [J].
BOYD, GD ;
STORZ, FG ;
MCFEE, JH ;
KASPER, HM .
IEEE JOURNAL OF QUANTUM ELECTRONICS, 1972, QE 8 (12) :900-+
[5]   Li2CdGeS4, A Diamond-Like Semiconductor with Strong Second-Order Optical Nonlinearity in the Infrared and Exceptional Laser Damage Threshold [J].
Brant, Jacilynn A. ;
Clark, Daniel J. ;
Kim, Yong Soo ;
Jang, Joon I. ;
Zhang, Jian-Han ;
Aitken, Jennifer A. .
CHEMISTRY OF MATERIALS, 2014, 26 (10) :3045-3048
[6]  
Chen C., 2012, Nonlinear, Optical Borate Crystals: Principles and Applications
[7]  
Chen J., 2020, ANGEW CHEM, V132, P5419
[8]   CsVO2F(IO3): An Excellent SHG Material Featuring an Unprecedented 3D [VO2F(IO3)]- Anionic Framework [J].
Chen, Jin ;
Hu, Chun-Li ;
Zhang, Xiao-Han ;
Li, Bing-Xuan ;
Yang, Bing-Ping ;
Mao, Jiang-Gao .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (13) :5381-5384
[9]   Multinary metal chalcogenides with tetrahedral structures for second-order nonlinear optical, photocatalytic, and photovoltaic applications [J].
Chen, Man-Man ;
Xue, Huai-Guo ;
Guo, Sheng-Ping .
COORDINATION CHEMISTRY REVIEWS, 2018, 368 :115-133
[10]  
Chen X., 2020, ANGEW CHEM, V132, P7584