Selective Oxidation of Aromatic Amines to Nitro Derivatives using Potassium Iodide-tert-Butyl Hydroperoxide Catalytic System

被引：75

作者：

Reddy, K. Rajender ^{[1
]}

Maheswari, C. Uma ^{[1
]}

Venkateshwar, M. ^{[1
]}

Kantam, M. Lakshmi ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Inorgan & Phys Chemsitry Div, Hyderabad 500607, Andhra Pradesh, India

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2009年 / 351卷 / 1-2期

关键词：

amines; nitroarenes; oxidation; peroxides; ALIPHATIC-AMINES; CHEMISTRY; ALCOHOLS; DIOXIRANES; ALDEHYDES; TEMPO; H2O2;

D O I：

10.1002/adsc.200800641

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The direct oxidation of aromatic primary amines to the corresponding nitro compounds selectively in 47-98% yields has been achieved by using potassium iodide as catalyst and tert-butyl hydroperoxide as the external oxidant. The present catalytic system works well for both electron-rich and electron-poor substrates.

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收藏

页码：93 / 96

页数：4

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