Grafting of η5-Cp(COOMe)MoCl(CO)3 on the surface of mesoporous MCM-41 and MCM-48 materials

被引：31
作者：
Sakthivel, A
Abrantes, M
Chiang, AST
Kühn, FE
机构：
[1] Tech Univ Munich, Lehrstuhl Anorgan Chem, D-85747 Garching, Germany
[2] Natl Cent Univ, Chungli 320, Taiwan
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 05期
关键词：
epoxidation; grafting; molybdenum; mesoporous materials; organometallic complex;
D O I：
10.1016/j.jorganchem.2005.10.054
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
eta(5)-Cp(COOMe)MoCl(CO)(3) is grafted on the surface of mesoporous MCM-41 and MCM-48 materials through available silanol groups. The structural intactness of the supporting materials is confirmed by powder XRD and N-2 adsorption analysis. The presence of the Mo complex on the surface is confirmed by FT-IR and elemental analysis. The catalysts are successfully applied for cyclooctene epoxidation. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：1007 / 1011
页数：5
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