Rate constant for the reaction CF3O+O-3->products by the fast flow absolute technique

被引：0

作者：

Bourbon, C

Brioukov, M

Devolder, P

机构：

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE A-SCIENCES DE LA TERRE ET DES PLANETES | 1996年 / 322卷 / 03期

关键词：

kinetics; CF3O; ozone; HCFC's;

D O I：

暂无

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

The rate constant k(5) of the reaction R(5) : CF3O + O-3 --> products has been measured at room temperature with the absolute Fast Flow tube technique in the pressure range 2-9 Torr. The CF3O radicals are generated by pyrolysis of the dimer CF3OOCF3 and their relative concentration is followed by Laser Induced Fluorescence. The CF3O/He mixture is flowed through the movable central injector whereas the reactant (ozone) is flowed into the main flow tube; this protocol allows a better control of the side reactions which compete with R(?)5. The average of our measurements leads to: k(5) = (1.3 +/- 0.5) x 10(-14) cm(3) molec(-1) s(-1) which is in reasonable agreement with the more recent determinations.

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页码：181 / 188

页数：8

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