Synthesis and Conductometric Property of Sol-Gel-Derived ZnO/PVP Nano Hybrid Films

被引：12

作者：

Ilegbusi, Olusegun J. ^{[1
]}

Trakhtenberg, Leonid I. ^{[2
]}

机构：

[1] Univ Cent Florida, Dept Mech Mat & Aerosp Engn, Orlando, FL 32816 USA

[2] Russian Acad Sci, Semonov Inst Chem Phys, Moscow, Russia

来源：

JOURNAL OF MATERIALS ENGINEERING AND PERFORMANCE | 2013年 / 22卷 / 03期

基金：

美国国家科学基金会;

关键词：

atomic force microscopy; conductometry; polymer nanocomposite; sol-gel; zinc oxide; ZINC-OXIDE FILMS; ZNO NANOPARTICLES; OXIDATION;

D O I：

10.1007/s11665-012-0336-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

ZnO nanoparticles immobilized in polyvinylpyrrolidone (PVP) were prepared using sol-gel dip-coating technique with varying Zn2+/PVP ratios. The films were characterized using atomic force microscopy, x-ray photoelectron spectroscopy, and Fourier transform infrared spectroscopy for chemical analysis. The size and concentration of ZnO particles decreased as the Zn/PVP ratio decreased. Under low Zn2+/PVP molar ratios, ZnO particles were clearly well separated and capped in the PVP polymer matrix. Electrical resistivity of 10(8) Omega cm was achieved under these deposition conditions.

引用

页码：911 / 915

页数：5

共 22 条

[1] Perspectives on the physical chemistry of semiconductor nanocrystals [J].

Alivisatos, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239

[2] Multicenter scattering theory of mediator effect in electron tunneling transitions [J].

Bolgov, DI ;

Kozhushner, MA ;

Muryasov, RR ;

Posvyanskii, VS .

JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (07) :3871-3882

[3] Influence of annealing temperature on the formation and characteristics of sol-gel prepared ZnO films [J].

Castanedo-Pérez, R ;

Jiménez-Sandoval, O ;

Jiménez-Sandoval, S ;

Márquez-Marín, J ;

Mendoza-Galván, A ;

Torres-Delgado, G ;

Maldonado-Alvarez, A .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1999, 17 (04) :1811-1816

[4] CHARACTERISTICS OF HIGH-QUALITY ZNO THIN-FILMS DEPOSITED BY PULSED-LASER DEPOSITION [J].

CRACIUN, V ;

ELDERS, J ;

GARDENIERS, JGE ;

BOYD, IW .

APPLIED PHYSICS LETTERS, 1994, 65 (23) :2963-2965

[5] Synthesis and morphological characterization on PVP/ZnO nano hybrid films [J].

Du, T ;

Ilegbusi, OJ .

JOURNAL OF MATERIALS SCIENCE, 2004, 39 (19) :6105-6109

[6] Highly monodisperse polymer-capped ZnO nanoparticles: Preparation and optical properties [J].

Guo, L ;

Yang, SH ;

Yang, CL ;

Yu, P ;

Wang, JN ;

Ge, WK ;

Wong, GKL .

APPLIED PHYSICS LETTERS, 2000, 76 (20) :2901-2903

[7] Synthesis and optical properties of crystalline polymer-capped ZnO nanorods [J].

Guo, L ;

Cheng, JX ;

Li, XY ;

Yan, YJ ;

Yang, SH ;

Yang, CL ;

Wang, JN ;

Ge, WK .

MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2001, 16 (1-2) :123-127

[8] Optical and electrical characteristics of aluminum-doped ZnO thin films prepared by solgel technique [J].

Jimenez-Gonzalez, AE ;

Urueta, JAS ;

Suarez-Parra, R .

JOURNAL OF CRYSTAL GROWTH, 1998, 192 (3-4) :430-438

[9] THICKNESS-DEPENDENT PROPERTIES OF INDIUM-DOPED ZNO FILMS [J].

MAJOR, S ;

BANERJEE, A ;

CHOPRA, KL ;

NAGPAL, KC .

THIN SOLID FILMS, 1986, 143 (01) :19-30

[10] CARBON NITRIDE DEPOSITED USING ENERGETIC SPECIES - A 2-PHASE SYSTEM [J].

MARTON, D ;

BOYD, KJ ;

ALBAYATI, AH ;

TODOROV, SS ;

RABALAIS, JW .

PHYSICAL REVIEW LETTERS, 1994, 73 (01) :118-121

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