Synthesis and characterization of dithia[3.3](2,6)pyridinophane-containing polymers: Application to the palladium-catalyzed Heck reaction

被引：23

作者：

Morisaki, Y ^{[1
]}

Ishida, T ^{[1
]}

Chujo, Y ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 06期

关键词：

D O I：

10.1021/ol0529290

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We synthesized zigzag polymers consisting of dithia[3.3](2,6)pyridinophane units that were flipped rapidly as a result of syn-[anti]-syn isomerization. Pyridinophane units were fixed in the syn form by complexation with palladium, and the resulting polymer complex exhibited a high catalytic activity for the Heck coupling reaction.

引用

页码：1029 / 1032

页数：4

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