Syntheses, Crystal Structures and Properties of Cu(II), Ni(II) and Cd(II) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1,2,4-triazole

被引：2

作者：

He Wei-Wei ^{[1
]}

Feng Si-Yang ^{[1
]}

Qu Zhi-Rong ^{[1
]}

Tang Hui ^{[2
]}

Wang Zuo-Xiang ^{[2
]}

机构：

[1] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Zhejiang, Peoples R China

[2] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2019年 / 35卷 / 01期

关键词：

4-methyl-3-phenyl-5-(2-pyridyl)-1,2,4-triazole; complexes; syntheses; crystal structures; fluorescence; LUMINESCENT; DERIVATIVES; POTENT; INHIBITORS; TRIAZOLES; BINDING; DESIGN; LIGAND;

D O I：

10.11862/CJIC.2019.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of [CuL(2)C1]Cl center dot H2O (1), [NiL2(H2O)(2)](NO3)(2) (2), [CuL2 (H2O)(2)](ClO4)(2) (3) and [CdL2(NO3)(2)]center dot CH3CN (4) were synthesized by the reactions of 4-methyl-3-phenyl-5-(2-pyridy1)-1,2,4-triazole (L) with CuCl2 center dot 2H(2)O, Ni(NO3)(2)center dot 6H(2)O, Cu(ClO4)center dot 6H(2)O and Cd(NO3)(2)center dot 4H(2)O, respectively. Their structures were determined by single crystal X-ray diffraction, and characterized by IR, UV-Vis, fluorescence and TGA. Complex 1 belongs to orthorhombic system with space group Fddd, and the central Cul (II) ion has a distorted tetragonal pyramid geometry [CuN4Cl]. The complexes of 2, 3 and 4 all belong to monoclinic system with space groups P2(1)/n, P2(1)/n and P2(1)/c, respectively. All the central metal ions of 2, 3 and 4 have distorted octahedral configuration [NiN4O2], [CuN4O2], [CdN4O2]. CCDC: 1854277, 1; 1854278, 2; 1854289, 3; 1854284, 4.

引用

页码：155 / 164

页数：10

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